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CAS No. : | 42075-32-1 | MDL No. : | MFCD00063893 |
Formula : | C5H12O2 | Boiling Point : | No data available |
Linear Structure Formula : | HOCH(CH3)CH2CH(CH3)OH | InChI Key : | GTCCGKPBSJZVRZ-RFZPGFLSSA-N |
M.W : | 104.15 | Pubchem ID : | 2723683 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P280-P301+P312-P302+P352-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 0℃; for 28h;Inert atmosphere; | Under nitrogen was added to the reaction flask 250mL diol 1 (2.080g, 20mmol), pyridine-2 (9.72 g, 44mmol), triphenylphosphine (12.6g, 48mmol), was added at 0 80mL of tetrahydrofuran was stirred to dissolve. From the pressure-equalizing dropping funnel was added dropwise a solution of DIAD (9.70g, 48mmol) in 20mL of tetrahydrofuranSolution, the addition was complete, the system was orange-red transparent solution. The reaction 28 hours, only a small amount of residual material, the first spin-dry tetrahydrofuran, was added 20mL dissolved in dichloromethane, adding a lot of petroleum ether, to have a large amount of solid precipitation (mostly reduction product of three phenoxy phosphine and DIAD in. If you can not precipitate with a spoon scraping the sides of the bottle repeatedly), when the suction (filtration the solid was washed several times with petroleum ether, gussets detect whether solid containing the desired product, if there are more products, then the solid was recrystallized again), the mother liquor recovered spin dry column chromatography to obtain an oily liquid - compound 3. |
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