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CAS No. : | 42013-20-7 | MDL No. : | MFCD00050991 |
Formula : | C10H11NO3 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | YOEBAVRJHRCKRE-UHFFFAOYSA-N |
M.W : | 193.20 | Pubchem ID : | 91637 |
Synonyms : |
2-Methylhippuric Acid;o-Toluric Acid;NSC 163983;2-MHA;ortho-Methylhippuric Acid;o-Methylhippuric Acid;2-Methylbenzoylglycine
|
Chemical Name : | 2-(2-Methylbenzamido)acetic acid |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
31% | With sodium acetate; acetic anhydride; In neat (no solvent); at 95℃; | General procedure: A mixture of <strong>[34595-26-1]2-(piperidin-1-yl)benzaldehyde</strong> (0.946 g, 5 mmol) and 2-benzamidoacetic acid (0.896 g, 5 mmol) was heated in 95 C with the addition of NaOAc (2.5 mmol) and Ac2O (5 mmol). After completion of the reaction, 2 mL ethanol was added to the mixture and was stirred for 10 h at room temperature. The solid was filtered off, washed with water, and ice-cold ethanol. The crude product was recrystallized from toluene to give the corresponding (Z)-alkylidene azlactones 1a (Note: For the preparation of compounds 1b-n, the corresponding crude products were recrystallized from ethanol to give the desired products 1b-n). |
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