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CAS No. : | 4132-48-3 | MDL No. : | MFCD00015033 |
Formula : | C10H14O | Boiling Point : | No data available |
Linear Structure Formula : | CH3OC6H4CH(CH3)2 | InChI Key : | JULZQKLZSNOEEJ-UHFFFAOYSA-N |
M.W : | 150.22 | Pubchem ID : | 77783 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P280 | UN#: | |
Hazard Statements: | H302-H312-H332 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
70% | With potassium phosphate monohydrate; tris(1-adamantyl)phosphine; {2-[((acetyl-kappaO)amino)phenyl-kappaC](tri-1-adamantylphosphine)palladium}(p-toluenesulfonate); In tetrahydrofuran; toluene; at 100℃; for 5h; | To a mixture of 4-chioroanisole (62 jiL, 0.50 mmol, 1 equiv), <strong>[80041-89-0]isopropylboronic acid</strong> (66 mg, 0.75 mmol, 1.5 equiv), and K3P04H20 (0.35 mg, 1.5 mmol, 3 equiv) was added a toluenestock solution of 3 and PAd3 (2 mL, 5 jimol of Pd/PAd3). The mixture was stirred at 100 C for 5 h. The reaction mixture was diluted with ethyl acetate then extracted with water. The combine organic layers were evaporated and the crude product was purified by flash chromatography. After drying, 53 mg (70%) of 44 was obtained as a colorless oil. NMR spectroscopic data agreed with literature values. |