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CAS No. : | 3383-72-0 | MDL No. : | MFCD00674505 |
Formula : | C8H8ClNO3 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | OBCFOPGCTNULTG-UHFFFAOYSA-N |
M.W : | 201.61 | Pubchem ID : | 2764587 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P280-P305+P351+P338-P310 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H332-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With potassium carbonate; potassium iodide; In N,N-dimethyl-formamide; at 100℃; for 4h;Inert atmosphere; | General procedure: Various secondary amines a-f (7.44 mmol) was added to a solution of1-(2-chloroethoxy)-4-nitrobenzene 9 (0.5 g, 2.48 mmol), anhydrous K2CO3 (1.71 g, 12.4 mol) andcatalytic amount of KI in DMF (10 mL), and the mixture was refluxed for 4 h at 100C under anargon atmosphere. After the reaction was completed, the mixture was slowly added to ice waterand extracted with EtOAc. The combined organic phases were washed sequentially with saturatedNaCl, and then dried over anhydrous Na2SO4, and evaporated to dryness under reduced pressureto give corresponding compounds 10a-f as yellow oil, which were used without furtherpurification. |
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