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CAS No. : | 32943-25-2 | MDL No. : | MFCD01632171 |
Formula : | C14H12ClN | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | MHUXTOYYIDFXRF-UHFFFAOYSA-N |
M.W : | 229.70 | Pubchem ID : | 118364 |
Synonyms : |
|
Chemical Name : | 3-Chloro-10,11-dihydro-5H-dibenzo[b,f]azepine |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P301+P312+P330 | UN#: | N/A |
Hazard Statements: | H302 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
86% | With triethyl borane; sodium hydroxide; In tert-butyl methyl ether; at 80℃; for 6h;Inert atmosphere; Sealed tube; | Under argon atmosphere,Firstly, NaOH and triethylboron are stirred to form a transparent clear solution at room temperature.The concentration is 1M/L;Then,The above triethylboron solution was successively treated with 10umol (2mol%),Amide substrate 5mmol,Triethoxysilane or polymethylhydrogensiloxane 15mmol,MTBE 2mL added to the 10mL sealed tube,It is heated and stirred in an 80C oil bath for 6 hours.The reaction is over,Exposing the reaction to air quenching,The amine product is then separated directly by column chromatography.According to the results of column chromatography separation, when using triethoxysilane or polymethylhydrogensiloxane (PMHS),The yield of the target product was: 86%, 75%. |