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CAS No. : | 29124-57-0 | MDL No. : | MFCD10696879 |
Formula : | C7H6BrNO | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | VBYZWJMZASVGNB-UHFFFAOYSA-N |
M.W : | 200.03 | Pubchem ID : | 23510475 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
51% | With hydrogenchloride; In water; at 100℃; for 4h; | Method of synthesising quinoline D.57Ethoxyacrylate ED.13 (6.4 mL, 44.3 mmol) is placed in MeOH (120 mL), combined with HCI (88 mL, 2M in H20) and heated to 100°C. Benzaldehyde ED.12 (4.00 g, 20.1 mmol) is placed in MeOH (120 mL), slowly added dropwise to the reaction mixture and the reaction mixture is heated to 100°C for 4 h. Then it is made basic with NaHC03, the solvent is eliminated, the residue is purified by chromatography (90:10 to 40:60 in 15 min hexane/EtOAc) and quinoline D.57 (4.08 g, 51 percent; HPLC-MS: MS(M+H)+ = 266/268; tRet = 1 .50 min; method LCMSBAS1 ) is obtained. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
51% | With hydrogenchloride; In methanol; water; at 100℃; for 4h; | Method of Synthesising Quinoline D.57Ethoxyacrylate ED.13 (6.4 mL, 44.3 mmol) is placed in MeOH (120 mL), combined with HCl (88 mL, 2M in H2O) and heated to 100° C. Benzaldehyde ED.12 (4.00 g, 20.1 mmol) is placed in MeOH (120 mL), slowly added dropwise to the reaction mixture and the reaction mixture is heated to 100° C. for 4 h. Then it is made basic with NaHCO3, the solvent is eliminated, the residue is purified by chromatography (90:10 to 40:60 in 15 min hexane/EtOAc) and quinoline D.57 (4.08 g, 51percent; HPLC-MS: MS (M+H)+=266/268; tRet=1.50 min; method LCMSBAS1) is obtained. |
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