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CAS No. : | 2215-89-6 | MDL No. : | MFCD00013988 |
Formula : | C14H10O5 | Boiling Point : | - |
Linear Structure Formula : | O((C6H4)(COOH))2 | InChI Key : | WVDRSXGPQWNUBN-UHFFFAOYSA-N |
M.W : | 258.23 | Pubchem ID : | 75183 |
Synonyms : |
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Chemical Name : | 4,4'-Oxybis(benzoic acid) |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
~ 100% | EXAMPLE 12 (Compound 12)Oxo-bis-1,4-benzamidophenoxyisobutyric Acid; A mixture of 5.26 g (0.02 mole) 4-oxy-bis-benzoic acid and 25 ml THF and 2.2 ml (0.02 mole) triethylamine is cooled in freezer and then 2.75 ml (0.02 mole) t-butylchloroformate is added while stirring. The product is cooled again in a freezer and 3.9 g (0.04 mole) 4-aminoisobutyric acid and 1 g sodium hydroxide in 5 ml cold water is added with 20 ml THF and the solution is stirred for 2 hours. It is then evaporated by blowing air becoming a thick syrup. Cold water is added and evaporated to remove the rest of the THF. It is then acidified with acetic acid and 1 g dithionite added. The white precipitate is cooled and filtered. It is washed with water and left at room temperature to dry. The product is a white solid. To recrystallize a sample of 250 mg is dissolved in 10 ml isopropanol diluted with water and refrigerated to recrystalize into a granular white powder which is dried at room temperature for one week . . . Total yield 6.35 g (about 100%).The structure is structure 12. C34H32N2O9; mw 610; mp212-215 C. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
68% | at 130℃; for 72h;Autoclave; High pressure; | General procedure: A solution of 4,4′-oxybis(benzoate) (0.10 mmol, 25.8 mg),1,3-bis(imidazol)propane (0.10 mmol, 17.6 mg) andCo(NO3)2·6H2O (0.10 mmol, 29.1 mg) in distilled water(15 mL) was placed in a Teflon-lined stainless steel vessel,heated to 130 C for 3 days and then cooled to roomtemperature over 24 h. The resulting solid was washed withmethanol and dried under vacuum. Purple block crystalsof SNUT-1 were obtained with a yield of 68% based oncobalt. Elemental analysis (%): calcd for C23H21N4O5.5Co(M = 500.37): C, 55.16; H, 4.20; N, 11.19. found: C, 55.36;H, 4.12; N, 11.41. IR (cm-1): 3440 (s), 3125 (w), 2917 (w),1617 (s), 1558 (m), 1500 (w), 1423 (m), 1350 (m), 1270 (w),1153 (w), 1091 (w), 997 (w) and 721 (m). |