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CAS No. : | 2210-24-4 | MDL No. : | MFCD00080617 |
Formula : | C9H9NO | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | BPCNEKWROYSOLT-UHFFFAOYSA-N |
M.W : | 147.17 | Pubchem ID : | 221792 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
76.4% | Magnesium bar (5eq., 1.0mmol, 24mg), selenium powder (5eq., 1.0mmol, 79mg), <strong>[103962-05-6]1-iodo-4-(trifluoromethoxy)benzene</strong> (7.5eq., 1.5mmol, 267uL) were added Put it into a stainless steel jar (10 mL), the diameter of the ball milling medium is 10 mm, add 1 ml of THF, tighten the stainless steel jar, and place it on a ball mill for grinding (Retsch MM 400, 60 min, 30 Hz); After grinding for 60 minutes, the stainless steel jar was opened in the air, N-phenylacrylamide (1 eq., 0.2 mmol, 29.4 mg) was added, the stainless steel jar was tightened, and the jar was placed on a ball mill for grinding (Retsch MM 400, 15 min, 5 Hz) , After grinding, the mixture was eluted from the silica gel with EA, the solvent was evaporated under reduced pressure, and 59.3 mg of pure product was obtained by flash column chromatography (SiO2, petroleum ether/ethyl acetate, 5:1-10:1). The rate was 76.4%. (method 1) |
[ 91811-13-1 ]
N-(4-(Ethylamino)phenyl)acetamide
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