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CAS No. : | 21744-88-7 | MDL No. : | MFCD11040232 |
Formula : | C10H10O | Boiling Point : | - |
Linear Structure Formula : | CHOCCH2CH2C6H5 | InChI Key : | SMYKJEFTTNCUSN-UHFFFAOYSA-N |
M.W : | 146.19 | Pubchem ID : | 11008055 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P280-P305+P351+P338-P304+P340-P405-P501 | UN#: | N/A |
Hazard Statements: | H302 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With Dess-Martin periodane; In dichloromethane; for 24h; | EXAMPLE 7C A solution of EXAMPLE 7B (1.14 g) and Dess-Martin reagent (3.4 g) in dichloromethane (25 mL) was stirred for 24 hours, filtered and concentrated. The concentrate was flash chromatographed on silica gel with 10% ethyl acetete/hexanes. | |
With pyridinium chlorochromate; In dichloromethane; at 20℃; for 12h;Molecular sieve; | [675] To a suspension of 173A and molecular sieves (powdered, activated, 4A) in DCM was added PCC (10 mmol). After stirring for 12 hr at RT, the reaction was filtered through silica gel, and concentrated to give crude aldehyde 173B, which was used for the next step without purification. |