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[Zn(1,4-bis(2-methylimidazol-1-methyl)benzene)(1,3-benzenediacetate)]·H2O}n[ No CAS ]
Yield
Reaction Conditions
Operation in experiment
47%
With sodium hydroxide; In water; at 90.0℃; for 3h;pH 7.0;Autoclave;
General procedure: A solution of H2aze (0.2mmol) in 8mL H2O was adjusted to pH 7 with dilute NaOH. Then bix (0.2mmol) and Zn(NO3)2·6H2O (0.2mmol) in 12mL H2O were added. The mixture was added to a 20mL Teflon-lined stainless autoclave and this was sealed and heated to 90C for 3days, then cooled to room temperature to give colorless crystals of 5 in 39% yield (0.040g).
[Cd(1,4-bis(2-methyl-imidazol-1-methyl)benzene)(mbda)]n[ No CAS ]
Yield
Reaction Conditions
Operation in experiment
56%
With sodium hydroxide; In ethanol; water; at 90.0℃; for 72h;Autoclave; High pressure;
The solution of bix (0.2 mmol) in 5 mL EtOH and Cd(NO3)2.6H2O(0.2 mmol) in 5 mL H2O were added to H2mbda (0.20 mmol) andNaOH (0.18 mmol) in 5 mL H2O. The mixture was added to a30 mL Teflon-lined stainless autoclave and this was sealed and heated to 90 C for 3 days and then cooled to room temperature to give the colorless crystals 3 (Yield: 0.064 g, 56% based on H2-mbda ligand). Anal. Calcd. for C26H26CdN4O4 (3) C, 54.70; H, 4.59;N, 9.82. Found: C, 54.62%; H, 4.53%; N, 9.78%. IR data (cm-1):1556s, 1508w, 1420w, 1396s, 1283w, 1155w, 1138w, 1000w,767w, 740s, 725m, 668m.
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