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CAS No. : | 192189-07-4 | MDL No. : | MFCD05864781 |
Formula : | C13H14INO2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | LOFWPZQNSUAMCV-UHFFFAOYSA-N |
M.W : | 343.16 | Pubchem ID : | 10497531 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P280 | UN#: | |
Hazard Statements: | H302-H317 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
85% | With triethylamine; In dichloromethane; at 20℃; for 12h; | A solution of triethylamine (24 g, 237.6 mmol) and di-tert-butyl dicarbonate (20.75 g, 95.07 mmol) was added to a solution of 3-iodo-lH-indole (23.1 g, 95.05 mmol) in dichloromethane (200 mL) , Stirring at room temperature for 12 hours, TLC detection of raw materials disappeared. Add water, ethyl acetate extraction, combined organic phase, anhydrous sodium sulfate drying, The solvent was removed by rotary evaporation to give the product (27.7 g, yield 85%). |
82% | With dmap; In dichloromethane; at 20℃; for 1h; | To a solution of 9 (2Og, 82mmol) in 2OmL of dry DCM was added Boc2O (2.7mg, 12.Ommoi) and DMAP (20mg, 0. i2mnmnol). The mixture was stirred at room temperature for ih. Then themixture was diluted with water (2OmL) and extracted with DCM (lOOmL). The organic layer was washed with brine (5OmL), dried over anhydrous Na2SO4, filtered and concentrated to dryness. The residue was purified by chromatograph column on silica gel to give product 10 (2.3g, yield: 82%). 1HNMR (400 MHz, CDC1): c1.66 (s. 9 H), 7.297.40 (m. 3 H), 7.72. (s, I H), 8.12 (d, J=7.6 Hz, I H). |
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