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CAS No. : | 18469-52-8 | MDL No. : | MFCD00468795 |
Formula : | C9H11NO2 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | AQBJGAUQEJFPKZ-UHFFFAOYSA-N |
M.W : | 165.19 | Pubchem ID : | 571728 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 | UN#: | |
Hazard Statements: | H315-H319 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
67% | Using the synthetic procedure outlined in General Scheme 2, 2-fluoro- cyclohexanone (2.00 g, 17.22 mmol) and methyl 4-(aminomethyl)benzoate (3.47 g, 17.22 mmol) were stirred at room temperature in dichloroethane (50 mL) for 5 minutes. Sodium triacetoxyhydroborate (5.11 g, 24.11 mmol) was then added and the reaction mixture was then stirred at room temperature for 16 h. Water was added to reaction mixture and stirred for 5 min. Layers were separated and the organic layer was washed with NaHC0 3 (s), water, dried with sodium sulfate and concentrated in vacuo to give crude product which was purified by column chromatography (silica gel) using ethyl acetate/hexane (0 to 100%). The desired product, methyl 4-(((2- fluorocyclohexyl)amino)methyl)benzoate (3.20g, 67%), was isolated as a clear oil. MS (m/z): 275.3 |