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CAS No. : | 183070-44-2 | MDL No. : | MFCD01317016 |
Formula : | C29H29NO6 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | GQIVAZYTLZQGHT-VWLOTQADSA-N |
M.W : | 487.54 | Pubchem ID : | 21345475 |
Synonyms : |
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Chemical Name : | Fmoc-P-carboxy-Phe(OtBu)-OH |
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P280-P301+P312-P302+P352-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
To a 00 C. solution of (S)-2-((((9H-fluoren-9-yl) methoxy)carbonyl)amino)-3-(4-(tert-butoxycarbonyl)phe- nyl)propanoic acid (Chem-Impex, 150 mg, 0.308 mmol) in DMF (2051 pi) was added EDC (70.8 mg, 0.369 mmol) followed by 3H-[1 ,2,3] -triazolo[4,5-b]pyridin-3-ol (50.3 mg, 0.369 mmol). Afier 10 mi (R)-1,2,3,4-tetrahydronaph- thalen- 1-amine (45.2 pi, 0.308 mmol) and N-methylmorpholine (101 pi, 0.923 mmol) were added and the resulting reaction mixture was allowed to warm to it slowly overnight. The reaction mixture was then diluted with EtOAc and washed with iN HC1 (2x) and 10% EiC1 (lx). The organic layer was then dried over MgSO4, filtered, and concentrated in vacuo to give crude tert-butyl 4-((S)-2- ((((9H-fluoren-9-yl)methoxy)carbonyl)amino)-3-oxo-3- (((R)-1 ,2,3,4-tetrahydronaphthalen-1 -yl)amino)propyl)benzoate (177 mg, 0.287 mmol, 93% yield) as a clear oil, which was used without further purification. MS(ESI) mlz 617.5 (M+H). |
A1398662[ 2973755-09-6 ]
(R)-2-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-3-(4-(tert-butoxycarbonyl)phenyl)propanoic acid
Reason: Optical isomers