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CAS No. : | 17823-40-4 | MDL No. : | MFCD00075282 |
Formula : | C7BrF4N | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | STJZOKCIEOTPDV-UHFFFAOYSA-N |
M.W : | 253.98 | Pubchem ID : | 620140 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P280-P305+P351+P338 | UN#: | |
Hazard Statements: | H302+H312+H332-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
69% | With sodium hydride; In tetrahydrofuran; at 0 - 60℃; for 15.5h; | To a solution of 4-bromo-2,3,5,6-tetrafluorobenzonitrile (0.356 g, 1.4 mmol), 9H-3,6,-diphenylcarbazole (2.01 g, 6 mmol) in anhydrous THF (15 mL), was added sodium hydride (60percent in mineral oil, 0.28 g, 7 mmol) at 0 °C. The resulting mixture was stirred at 0 °C for 30 min, then 60 °C for 15 hours. Yellow precipitate formed, and diluted with THF (200 mL), washed with brine, dried over Na2So4, loaded on silica gel and purified by flash column using eluents of dichloromethane/hexane (30percent to 100percent). The desired fractions were collected, concentrated and filtrtation to give a yellow solid (Compound 23) (1.4 g, in 69percentyield). |