天堂网亚洲,天天操天天搞,91视频高清,菠萝蜜视频在线观看入口,美女视频性感美女视频,95丝袜美女视频国产,超高清美女视频图片

Home Cart 0 Sign in  

[ CAS No. 172217-11-7 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 172217-11-7
Chemical Structure| 172217-11-7
Structure of 172217-11-7 * Storage: {[proInfo.prStorage]}

Please Login or Create an Account to: See VIP prices and availability

Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Search after Editing

* Storage: {[proInfo.prStorage]}

* Shipping: {[proInfo.prShipping]}

Quality Control of [ 172217-11-7 ]

Related Doc. of [ 172217-11-7 ]

Alternatived Products of [ 172217-11-7 ]
Product Citations

Product Details of [ 172217-11-7 ]

CAS No. :172217-11-7 MDL No. :MFCD08275014
Formula : C9H10ClNO2 Boiling Point : -
Linear Structure Formula :- InChI Key :PKUFWXUXRIMHLM-UHFFFAOYSA-N
M.W : 199.63 Pubchem ID :15192435
Synonyms :

Safety of [ 172217-11-7 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P273-P305+P351+P338 UN#:N/A
Hazard Statements:H315-H319-H335-H412 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 172217-11-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 172217-11-7 ]

[ 172217-11-7 ] Synthesis Path-Downstream   1~2

  • 1
  • [ 172217-11-7 ]
  • [ 112270-06-1 ]
  • 2
  • [ 7664-93-9 ]
  • [ 172217-11-7 ]
  • [ 112270-06-1 ]
YieldReaction ConditionsOperation in experiment
With sodium nitrite; In water; Petroleum ether; A solution of sodium nitrite (4.5 g) in water (100 ml) was added dropwise during 5 minutes to a stirred suspension of ethyl 6-chloroanthranilate (12.7 g) in a mixture of concentrated sulphuric acid (27.9 ml), water (38 ml) and ice (76 g). The reaction mixture was stirred at 0C for an additional 20 minutes and then heated to 120C for 1 hour. The resultant mixture was poured into a mixture of ice and water and the product was extracted with diethyl ether. The organic phase was washed in turn with water and brine, dried over magnesium sulphate and evaporated. The residue was purified by column chromatography on silica using a 4:1 mixture of petroleum ether (b.p. 60-80C) and methylene chloride as eluent. There was thus obtained ethyl 6-chloro-2-hydroxybenzoate (9.8 g); NMR Spectrum : (DMSOd6) 1.3 (t, 3H), 4.3 (q, 2H), 6.9 (d, 1H), 6.95 (d, 1H), 7.25 (d, 1H), 10.45 (br s, 1H).
With sodium nitrite; In water; Petroleum ether; A solution of sodium nitrite (4.5 g) in water (100 ml) was added dropwise during 5 minutes to a stirred suspension of ethyl 6-chloroanthranilate (12.7 g) in a mixture of concentrated sulphuric acid (27.9 ml), water (38 ml) and ice (76 g). The reaction mixture was stirred at 0 C. for an additional 20 minutes and then heated to 120 C. for 1 hour. The resultant mixture was poured into a mixture of ice and water and the product was extracted with diethyl ether. The organic phase was washed in turn with water and brine, dried over magnesium sulphate and evaporated. The residue was purified by column chromatography on silica using a 4:1 mixture of petroleum ether (b.p. 60-80 C.) and methylene chloride as eluent. There was thus obtained ethyl 6-chloro-2-hydroxybenzoate (9.8 g); NMR Spectrum: (DMSOd6) 1.3 (t, 3H), 4.3 (q, 2H), 6.9 (d, 1H), 6.95 (d, 1H), 7.25 (d, 1H), 10.45 (br s, 1H).
Recommend Products
Same Skeleton Products

Technical Information

Historical Records

Related Functional Groups of
[ 172217-11-7 ]

Aryls

Chemical Structure| 1619264-45-7

[ 1619264-45-7 ]

Methyl 2-amino-6-chlorobenzoate hydrochloride

Similarity: 0.97

Chemical Structure| 5900-58-3

[ 5900-58-3 ]

Methyl 2-amino-4-chlorobenzoate

Similarity: 0.90

Chemical Structure| 20776-63-0

[ 20776-63-0 ]

2-Amino-4,6-dichlorobenzoic acid

Similarity: 0.87

Chemical Structure| 46004-37-9

[ 46004-37-9 ]

Methyl 4-amino-2-chlorobenzoate

Similarity: 0.87

Chemical Structure| 3032-32-4

[ 3032-32-4 ]

2-Amino-3,6-dichlorobenzoic acid

Similarity: 0.86

Chlorides

Chemical Structure| 1619264-45-7

[ 1619264-45-7 ]

Methyl 2-amino-6-chlorobenzoate hydrochloride

Similarity: 0.97

Chemical Structure| 5900-58-3

[ 5900-58-3 ]

Methyl 2-amino-4-chlorobenzoate

Similarity: 0.90

Chemical Structure| 20776-63-0

[ 20776-63-0 ]

2-Amino-4,6-dichlorobenzoic acid

Similarity: 0.87

Chemical Structure| 46004-37-9

[ 46004-37-9 ]

Methyl 4-amino-2-chlorobenzoate

Similarity: 0.87

Chemical Structure| 3032-32-4

[ 3032-32-4 ]

2-Amino-3,6-dichlorobenzoic acid

Similarity: 0.86

Esters

Chemical Structure| 1619264-45-7

[ 1619264-45-7 ]

Methyl 2-amino-6-chlorobenzoate hydrochloride

Similarity: 0.97

Chemical Structure| 5900-58-3

[ 5900-58-3 ]

Methyl 2-amino-4-chlorobenzoate

Similarity: 0.90

Chemical Structure| 46004-37-9

[ 46004-37-9 ]

Methyl 4-amino-2-chlorobenzoate

Similarity: 0.87

Chemical Structure| 294190-18-4

[ 294190-18-4 ]

Methyl 3-amino-5-chloro-2-methylbenzoate

Similarity: 0.86

Chemical Structure| 55150-07-7

[ 55150-07-7 ]

Methyl 5-chloro-2-(methylamino)benzoate

Similarity: 0.85

Amines

Chemical Structure| 1619264-45-7

[ 1619264-45-7 ]

Methyl 2-amino-6-chlorobenzoate hydrochloride

Similarity: 0.97

Chemical Structure| 5900-58-3

[ 5900-58-3 ]

Methyl 2-amino-4-chlorobenzoate

Similarity: 0.90

Chemical Structure| 20776-63-0

[ 20776-63-0 ]

2-Amino-4,6-dichlorobenzoic acid

Similarity: 0.87

Chemical Structure| 46004-37-9

[ 46004-37-9 ]

Methyl 4-amino-2-chlorobenzoate

Similarity: 0.87

Chemical Structure| 3032-32-4

[ 3032-32-4 ]

2-Amino-3,6-dichlorobenzoic acid

Similarity: 0.86

; ;