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CAS No. : | 145543-83-5 | MDL No. : | MFCD13193238 |
Formula : | C12H19BrS | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | ISONQKSIWXLJOQ-UHFFFAOYSA-N |
M.W : | 275.25 | Pubchem ID : | 10754854 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P280-P305+P351+P338 | UN#: | |
Hazard Statements: | H302 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
71% | 500mL three-necked flask was added magnesium tablets (10g) and 100mL ether under argon was added dropwise 2_ bromo-3-octylthiophene (35g) and 1,2-dibromoethane (5.65g) in 50mL of ether After the addition, reflux for three hours. After the reaction was completed, the reaction solution was added dropwise to the solution2,5-dibromo-bithiophene(15.87 g), Ni (dppp) 2 Cl2 (1.59 g) and 100 mL of diethyl etherThree bottles, after adding, reflux overnight. After completion of the reaction, dilute hydrochloric acid was added and the mixture was extracted with dichloromethane, dried over anhydrous sodium sulfate,The organic solvent was removed and the column was separated to give a light yellow liquid, Intermediate 4 (19.22 g, 71% yield). |
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