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CAS No. : | 1413732-47-4 | MDL No. : | MFCD31707622 |
Formula : | C11H8CuF3N2S | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 320.80 | Pubchem ID : | - |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 | UN#: | |
Hazard Statements: | H315-H319 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
97% | In acetonitrile; at 20℃; for 8h; | General procedure: Benzyl bromide 1 (0.17mmol), [(bpy)Cu(SCF3)] (80mg, 0.25mmol, 1.5equiv), and CH3CN (1.0mL) were added to a reaction tube equipped with a stir bar. The mixture was stirred at room temperature for 8-24h until the reaction was judged complete by TLC analysis. The reaction mixture was filtered through a pad of Celite. The filtrate was added water (3×10mL) at 0C. The resulting mixture was extracted with Et2O (3×15mL), and the combined organic layers was washed with water, and then dried over MgSO4. The solvent was removed to give the desired product 3 without further purification. |