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CAS No. : | 139962-95-1 | MDL No. : | MFCD01319043 |
Formula : | C8H9BO4 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | ZSSNGMFKYFBOAG-UHFFFAOYSA-N |
M.W : | 179.97 | Pubchem ID : | 2734365 |
Synonyms : |
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Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
51% | With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tetrakis(triphenylphosphine) palladium(0); caesium carbonate; In ethanol; toluene; at 150℃; for 0.166667h;Microwave irradiation; | General procedure: To a thick-well borosilicate glass vial (10 mL) was added phenyl propanone starting materials (0.20 g, 0.94 mmol), 4-methoxy-2-formyl boronic acid (0.20 g, 1.12 mmol), Pd (PPh3)4 (0.043 g, 4mol %), Cs2CO3 ( 0.91 g, 2.82 mmol) and S-Phos (0.022 g, 6 mol%) sequentially in a toluene: ethanol (4 mL:2 mL) mixture. The reaction vial was then sealed and placed in a microwave reactor and irradiated with 60-80 W power at 150 C for 10 min. The reaction mixture was then cooled to room temperature and diluted with excess ethyl acetate. The resulting solution was filtered through celite and concentrated in vacuo. The crude solid was purified by column chromatography (10-15% ethyl acetate/hexane). |