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CAS No. : | 13570-00-8 | MDL No. : | MFCD08458369 |
Formula : | C8H7N3 | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | ZQZJULZPQACTES-UHFFFAOYSA-N |
M.W : | 145.16 | Pubchem ID : | 12395500 |
Synonyms : |
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Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
12.49 g | With potassium carbonate; In N,N-dimethyl-formamide; at 20℃; for 7h; | (1) In DMF (70 mE) was dissolved 3-(1H-imidazol-2-yl) pyridine (10 g, 68.9 mmol) which is publicly known through publication, potassium carbonate (19 g, 138 mmol) and 2,5- dichlorobenzyl bromide (19.83 g, 83 mmol) were added thereto, and the mixture was stirred at room temperature for 7 hours. After the reaction, water was added and the mixture was extracted twice with ethyl acetate (100 mE). Afier being washed with saturated aqueous sodium chloride, the organic layer was dried over anhydrous sodium sulfate. After concentrating the organic layer, the residue was purified by column chromatography to obtain 3-O-(2,5-dichlorobenzyl)- 1 H-imidazol-2-yl)pyridine (12.49 g):10189] ?H-NMR (DMSO-d5) oe: 8.71 (1H, d, J=2.0 Hz),8.58 (1H, dd, J=4.9, 1.5 Hz), 7.92 (1H, dt, J=8.1, 2.0 Hz),7.52-7.36 (4H, m), 7.15 (1H, d, J=1.5 Hz), 6.81 (1H, d, J=2.4 Hz), 5.41 (2H, s);10190] ESI-MS mlz=304 (M+H). |
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