Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | ||||||
{[ item.p_purity ]} | {[ item.pr_size ]} | Inquiry |
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,1,item.pr_is_large_size_no_price) ]} |
{[ getRatePrice(item.pr_usd, 1,1,item.pr_is_large_size_no_price) ]} | Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate,item.pr_is_large_size_no_price) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate,item.pr_is_large_size_no_price) ]} | {[ item.pr_usastock ]} | in stock Inquiry - | {[ item.pr_chinastock ]} | {[ item.pr_remark ]} in stock Inquiry - | Login | Inquiry |
Please Login or Create an Account to: See VIP prices and availability
CAS No. : | 1129-26-6 | MDL No. : | MFCD00025392 |
Formula : | C7H9NO3S | Boiling Point : | - |
Linear Structure Formula : | CH3O(C6H4)SO2NH2 | InChI Key : | MSFQEZBRFPAFEX-UHFFFAOYSA-N |
M.W : | 187.22 | Pubchem ID : | 70789 |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
0.037 g (19%) | In N,N-dimethyl-formamide; | EXAMPLE 198 3-Bromo-2[-(4-methoxybenzenesulfonyl)amino]-benzoic acid methyl ester To 0.096 g (0.5 mmol) of 4-methoxyphenylsulphonamide in 3 mL of DMF was added in one portion 0.020 g (0.50 mmol) of 60percent sodium hydride and the reaction was stirre at 25° C. for 15 min. Then, 0.135 g (0.58 mmol) of <strong>[206551-41-9]methyl 3-bromo-2-fluorobenzylate</strong> was added to the solution in one portion and the resulting mixture was heated at 90° C. (bath temperature) for 18 h. The reaction was cooled to room temperature, acidified with 1N HCl and extracted with ethyl acetate. The combined organic layers were dried over magnesium sulfate, filtered and concentrated in vacuo. The residue was chromatographed on silica eluding with 30percent-50percent ethyl acetate/hexane to provide 0.037 g (19percent) of the desired product. 1 H-NMR(CDCl3): 8 ppm (s, 1H, NH), 6.8-7.8 ppm (m, 7H, Ar), 3.9 ppm (s, 1H, OMe), 3.7 ppm (s, 1H, OMe). |
0.037g (19%) | In N,N-dimethyl-formamide; | Example 198 3-Bromo-2[-(4-methoxybenzenesulfonyl)amino]-benzoic acid methyl ester To 0.096g (0.5 mmol) of 4-methoxyphenylsulphonamide in 3mL of DMF was added in one portion 0.020g (0.50 mmol) of 60percent sodium hydride and the reaction was stirred at 25-C for 15 min. Then, 0.135g (0.58 mmol) of <strong>[206551-41-9]methyl 3-bromo-2-fluorobenzylate</strong> was added to the solution in one portion and the resulting mixture was heated at 90 °C (bath temperature) for 18h. The reaction was cooled to room temperature, acidified with 1N HCl and extracted with ethyl acetate. The combined organic layers were dried over magnesium sulfate, filtered and concentrated in vacuo. The residue was chromatographed on silica eluding with 30percent-50percent ethyl acetate/hexane to provide 0.037g (19percent) of the desired product. 1H-NMR(CDCl3): 8 ppm (s, 1H, NH), 6.8-7.8 ppm (m, 7H, Ar), 3.9 ppm (s, 1H, OMe), 3.7 ppm (s, 1H, OMe). |
[ 82031-33-2 ]
2-(2-Methoxyethoxy)benzenesulfonamide
Similarity: 0.91
[ 1513-45-7 ]
4-(Trifluoromethoxy)benzenesulfonamide
Similarity: 0.84
[ 860515-97-5 ]
4-(4-Bromophenoxy)benzenesulfonamide
Similarity: 0.83
[ 32327-46-1 ]
5-Methoxynaphthalene-1-sulfonamide
Similarity: 0.79
[ 82031-33-2 ]
2-(2-Methoxyethoxy)benzenesulfonamide
Similarity: 0.91
[ 1513-45-7 ]
4-(Trifluoromethoxy)benzenesulfonamide
Similarity: 0.84
[ 860515-97-5 ]
4-(4-Bromophenoxy)benzenesulfonamide
Similarity: 0.83
[ 37526-59-3 ]
2-(Trifluoromethoxy)benzenesulfonamide
Similarity: 0.79
[ 32327-46-1 ]
5-Methoxynaphthalene-1-sulfonamide
Similarity: 0.79
[ 82031-33-2 ]
2-(2-Methoxyethoxy)benzenesulfonamide
Similarity: 0.91
[ 1513-45-7 ]
4-(Trifluoromethoxy)benzenesulfonamide
Similarity: 0.84
[ 860515-97-5 ]
4-(4-Bromophenoxy)benzenesulfonamide
Similarity: 0.83
[ 32327-46-1 ]
5-Methoxynaphthalene-1-sulfonamide
Similarity: 0.79
[ 82031-33-2 ]
2-(2-Methoxyethoxy)benzenesulfonamide
Similarity: 0.91
[ 1513-45-7 ]
4-(Trifluoromethoxy)benzenesulfonamide
Similarity: 0.84
[ 860515-97-5 ]
4-(4-Bromophenoxy)benzenesulfonamide
Similarity: 0.83
[ 32327-46-1 ]
5-Methoxynaphthalene-1-sulfonamide
Similarity: 0.79