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CAS No. : | 100523-96-4 | MDL No. : | MFCD03085768 |
Formula : | C5H3BrIN | Boiling Point : | No data available |
Linear Structure Formula : | - | InChI Key : | HPKRNLGLZYOVJS-UHFFFAOYSA-N |
M.W : | 283.89 | Pubchem ID : | 1051520 |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | |
Hazard Statements: | H315-H319-H335 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
33 mg | With potassium phosphate; copper(l) iodide; (1R,2R)-1,2-diaminocyclohexane; In 1,4-dioxane; at 110℃; for 24h; | <strong>[145901-11-7]1H-pyrrolo[2,3-b]pyridin-6-amine</strong> (57 mg, 0.42 mmol), 2-bromo-4-iodopyridine (100 mg, 0.35 mmol), potassium phosphate (156 mg, 0.73 mmol) and trans Cyclohexanediamine (40 mg, 0.35 mmol) was added to aneggplant type flask, and 1,4-dioxane was added thereto, and the reaction solution was deoxidized. Copper iodide(7 mg, 0.036 mmol) was added and the reaction solution was deoxygenated. Heat to 110 C and stir for 24hours. After the reaction was completed, it was cooled to room temperature, water and ethyl acetate were added,and the mixture was filtered over Celite. The target compound was obtained in 33 mg. |
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