REVIEW It is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis, for example, metal ketimines to form enantiopure sulfinimines; p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine.
REFERENCES
[1]
Asymmetric synthesis and properties of sulfinimines (thiooxime S-oxides). Davis FA, et al. The Journal of Organic Chemistry 62(8), 2555-2563, (1997)
[2]
Asymmetric synthesis of the antibiotic (+)-thiamphenicol using cis-N-(p-toluenesulfinyl) aziridine 2-carboxylic acids Davis FA and Zhou P. Tetrahedron Letters 35(41), 7525-7528, (1994)
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