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Postion:Product Catalog >Organic Chemistry>Phosphines>Benzyltriphenylphosphonium bromide
Benzyltriphenylphosphonium bromide
  • Benzyltriphenylphosphonium bromide
  • Benzyltriphenylphosphonium bromide
  • Benzyltriphenylphosphonium bromide
  • Benzyltriphenylphosphonium bromide
  • Benzyltriphenylphosphonium bromide

Benzyltriphenylphosphonium bromide NEW

Price Get Latest Price
Package 25KG
Min. Order: 1KG
Supply Ability: 50000KG/month
Update Time: 2023-09-04

Product Details

Product Name: Benzyltriphenylphosphonium bromide CAS No.: 1449-46-3
EC-No.: 215-908-4 Min. Order: 1KG
Purity: 99% Supply Ability: 50000KG/month
Release date: 2023/09/04

CAS:1449-46-3
MF:C25H22BrP
MW:433.32
EINECS:215-908-4
Product Categories:Phosphonium Compounds;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;Wittig Reaction;C-C Bond Formation;Olefination;Pharmaceutical Intermediates;Wittig Reagents
Mol File:1449-46-3.mol
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Benzyltriphenylphosphonium bromide Chemical Properties
Melting point 295-298 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form solid
color White to Almost white
Water Solubility Soluble in water.
Sensitive Hygroscopic
BRN 3599867
CAS DataBase Reference1449-46-3(CAS DataBase Reference)
Benzyltriphenylphosphonium bromide Usage And Synthesis
PreparationBenzyl triphenylphosphonium bromide is prepared by the following steps:To a solution of Ph3P (22 g, 0.084 mol) in toluene, BnBr (10 ml, 0.084 mol) was  added dropwise with ice-cooling and stirred at room temperature for 2 hours. A solid was  formed, which was filtered and washed with toluene and then dry pet ether to remove  unreacted Ph3P. The salt was dried under vacuum (35 g, 96% yield).
Chemical PropertiesWHITE CRYSTALLINE POWDER
UsesBenzyltriphenylphosphonium bromide is used as a reactant for stereoselective azidolysis of vinyl epoxides, enantioselective aziridination and Friedel-Crafts cyclization for asymmetric synthesis of dihydrexidine, biomimetic iron(III) mediated oxidative dimerization for synthesis of benzoquinone parvistemin A, enantioselective synthesis of syn-diarylheptanoids from D-glucose, preparation of β-amyloid plaque ligands and decarboxylative cyclopropanation. It react with 4-methyl-oxetan-2-one to produce 4-hydroxy-1-phenyl-1-(triphenyl-l5-phosphanylidene)-pentan-2-one.

Packing &shipping&Payment

Packing:25kg/drum
Shipping:by sea or by air
Payment:T/T,western union,moneygram
Packaging Details drum
Port:Tianjin
Lead Time :
Quantity(Kilograms)1 - 10000>10000
Est. Time(days)5To be negotiated

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Article illustrationCompany information
Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in 4'-Methylacetophenone,Levamisole hydrochloride ,N-Methylformamide and other chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big customers come from Europe, America and other countries in the world, we can guarantee the quality and price. In recent decades, with the efforts of all employees, we have established many cooperative companies in shandong, henan, guangdong and other places. Our corporate purpose is based on the market, enhance the strength, take the road of scientific and environmental sustainable development, relying on the country. Technology r & d center, increase the investment in r & d, based on the domestic market, expand the international market, manufacturing quality products, sincere service to the society, into a modern, ecological, scientific and technological enterprise world.

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