1-Butyl-3-methylimidazolium hexafluorophosphate
Price | Get Latest Price |
Package | 1kg |
Min. Order: | 1kg |
Supply Ability: | 100kg |
Update Time: | 2023-03-20 |
Product Details
Product Name: 1-Butyl-3-methylimidazolium hexafluorophosphate | CAS No.: 174501-64-5 |
EC-No.: 678-095-9 | Min. Order: 1kg |
Purity: 98.0%min | Supply Ability: 100kg |
Release date: 2023/03/20 | |
Package: Alum. foil bag, fibber carton, glass bottle etc. | Shipment: work with professional shipping agent |
Contact: marsha@lychems.cn |
1-Butyl-3-methylimidazolium hexafluorophosphate Basic information |
Product Name: | 1-Butyl-3-methylimidazolium hexafluorophosphate |
Synonyms: | 1-Butyl-3-methylimidazolium hexafluorophosphate≥ 98.5%(HPLC);1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE;1-BUTYL-3-METHYLIMIDAZOLIUM HEXFLUOROPHOSPHATE;1-Butyl-3-MethyliMidazoliuM hexafluorophosphate >=97.0% (HPLC);1-butyl-3-methylimmidazolium hexafluorophosphate;1-Butyl-3-methylimidazolium hexafluorophosphate for catalysis, >=98.5% (T);1-butyl-3-methylimidazolium hexafluorophsphate;JACS-174501-64-5 |
CAS: | 174501-64-5 |
MF: | C8H15F6N2P |
MW: | 284.18 |
EINECS: | 678-095-9 |
1-Butyl-3-methylimidazolium hexafluorophosphate Chemical Properties |
Melting point | 6.5 °C |
Boiling point | >340°C |
density | 1.38 g/mL at 20 °C (lit.) |
refractive index | n |
Fp | >350°C |
storage temp. | Store below +30°C. |
solubility | Acetone, Methanol |
form | Viscous Liquid |
Specific Gravity | 1.396 |
color | Clear colorless to pale yellow |
PH | 5 (H2O, 20℃) |
Water Solubility | Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane. |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
Uses | those consisting of tetrafluoroborate, alkylsulfate, alkylsulfonate, carboxylate, or phosphate anions are hydrophilic and are completely dissolved in water. Dupont and coworkers first reported stable hydrophobic imidazolium salt, 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) in 1996. Since then, this salt has been used as a typical hydrophobic IL in many chemical reactions because its mixture with water forms a biphasic layer. Furthermore, this IL shows poor solubility in hexane or ether, which allows realization of an easy work-up process. However, [C4mim][PF6] was reported to be sensitive to the moisture at high temperature and produced hazardous hydrogen fluoride as it decomposed. Therefore, bis(trifluoromethanesulfonyl)amide (NTf2) salts are now recommended as the anion for preparing hydrophobic ILs. |
Uses | 1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid employed in many environmentally friendly reactions. It can also be used as a medium for reactions such as:
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