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Postion:Product Catalog >Chemical Reagents>Organic reagents>Ionic Liquids>1-Butyl-3-methylimidazolium hexafluorophosphate
1-Butyl-3-methylimidazolium hexafluorophosphate
  • 1-Butyl-3-methylimidazolium hexafluorophosphate

1-Butyl-3-methylimidazolium hexafluorophosphate

Price Get Latest Price
Package 1kg
Min. Order: 1kg
Supply Ability: 100kg
Update Time: 2023-03-20

Product Details

Product Name: 1-Butyl-3-methylimidazolium hexafluorophosphate CAS No.: 174501-64-5
EC-No.: 678-095-9 Min. Order: 1kg
Purity: 98.0%min Supply Ability: 100kg
Release date: 2023/03/20
Package: Alum. foil bag, fibber carton, glass bottle etc. Shipment: work with professional shipping agent
Contact: marsha@lychems.cn
1-Butyl-3-methylimidazolium hexafluorophosphate Basic information
Product Name:1-Butyl-3-methylimidazolium hexafluorophosphate
Synonyms:1-Butyl-3-methylimidazolium hexafluorophosphate≥ 98.5%(HPLC);1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE;1-BUTYL-3-METHYLIMIDAZOLIUM HEXFLUOROPHOSPHATE;1-Butyl-3-MethyliMidazoliuM hexafluorophosphate >=97.0% (HPLC);1-butyl-3-methylimmidazolium hexafluorophosphate;1-Butyl-3-methylimidazolium hexafluorophosphate for catalysis, >=98.5% (T);1-butyl-3-methylimidazolium hexafluorophsphate;JACS-174501-64-5
CAS:174501-64-5
MF:C8H15F6N2P
MW:284.18
EINECS:678-095-9
1-Butyl-3-methylimidazolium hexafluorophosphate Chemical Properties
Melting point 6.5 °C
Boiling point >340°C
density 1.38 g/mL at 20 °C (lit.)
refractive index n20/D 1.41
Fp >350°C
storage temp. Store below +30°C.
solubility Acetone, Methanol
form Viscous Liquid
Specific Gravity1.396
color Clear colorless to pale yellow
PH5 (H2O, 20℃)
Water Solubility Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
Usesthose consisting of tetrafluoroborate, alkylsulfate, alkylsulfonate, carboxylate, or phosphate anions are hydrophilic and are completely dissolved in water. Dupont and coworkers first reported stable hydrophobic imidazolium salt, 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) in 1996. Since then, this salt has been used as a typical hydrophobic IL in many chemical reactions because its mixture with water forms a biphasic layer. Furthermore, this IL shows poor solubility in hexane or ether, which allows realization of an easy work-up process. However, [C4mim][PF6] was reported to be sensitive to the moisture at high temperature and produced hazardous hydrogen fluoride as it decomposed. Therefore, bis(trifluoromethanesulfonyl)amide (NTf2) salts are now recommended as the anion for preparing hydrophobic ILs.
Uses1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid employed in many environmentally friendly reactions.

It can also be used as a medium for reactions such as:
  • Ring-closing metathesis of diene and enyne substrates in the presence of a novel recyclable ruthenium carbene complex.

  • Nickel(II)acetylacetonate catalyzed oxidation of aromatic aldehydes to the corresponding acids using dioxygen as the oxidant.

  • Lipase-catalyzed enantioselective acylation of allylic alcohols.

  • Allylation of aldehydes using tetraallylstannane to yield homoallylic alcohols.


Company Profile Introduction

LY Global Chemicals Co Ltd.. is a limited liability company specialized in technical research and development, production, development and trade of chemical products. Mainly engaged in the customization and sales of pharmaceutical intermediates, electronic materials, cosmetics raw materials and other fine chemicals. We have many years of export experience, and our customers are all over many countries. Our products are of good quality, competitive price, stable supply, and customers are very satisfied

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