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(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Struktur
192139-90-5
CAS-Nr.
192139-90-5
Englisch Name:
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
Synonyma:
RuCl(p-cymene)[(S,S)-Ts-DPEN];RuCl[(S,S)- Tsdpen](p-cyMene);(S,S)-N-(p-ToL;)-1,2-diphenyL;ethanediamine(chL;-N-(p-Toluenesulfonyl);oro)(p-cymene)ruthenium(II);-1,2-diphenylethanediamine(chloro);[RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)];RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore
CBNumber:
CB91569347
Summenformel:
C31H30ClN2O2RuS
Molgewicht:
631.17
MOL-Datei:
192139-90-5.mol

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Eigenschaften

Schmelzpunkt:
>175 °C
alpha 
178o (C=0.5 IN CHLOROFORM)
storage temp. 
2-8°C
L?slichkeit
soluble in Chloroform, DCM, Ethyl Acetate
Aggregatzustand
solid
Farbe
yellow to dark brown
Optische Aktivit?t
[α]20/D +178°, c = 0.5 in chloroform
Sensitive 
air sensitive
InChIKey
DCJKLKCGNMDXFR-MNPNNRAMNA-M
SMILES
[Cl-][Ru+2]123456(N[C@@H](C7C=CC=CC=7)[C@H](C7C=CC=CC=7)[N-]1S(C1C=CC(C)=CC=1)(=O)=O)C1(C)C2=C3C4(C(C)C)=C5C6=1 |&1:3,10,r|
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn
R-S?tze: 22
S-S?tze: 24/25
WGK Germany  3
HS Code  28439000
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

Solid

Verwenden

Catalyst involved in: ? Asymmetric transfer hydrogenation of imines and ketones ? Intramolecular asymmetric reductive amination ? Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of arenerut

Allgemeine Beschreibung

RuCl(p-cymene)[(S,S)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.

(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 181)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621
sales@runvmat.com China 403 58
Hangzhou ICH Biofarm Co., Ltd
+86-0571-28186870; +undefined8613073685410
sales@ichemie.com China 1001 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806
sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
info@dakenam.com China 18751 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070
product@chemlin.com.cn CHINA 3009 60
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32957 60
career henan chemical co
+86-0371-86658258 +8613203830695
sales@coreychem.com China 29880 58
Shenzhen Nexconn Pharmatechs Ltd
+86-755-89396905 +86-15013857715
admin@nexconn.com China 10311 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28172 58

192139-90-5()Verwandte Suche:


  • -1,2-diphenylethanediamine(chloro)
  • -N-(p-Toluenesulfonyl)
  • (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
  • Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • [N-[(1S,2S)-2-(Amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-n)-1-methyl-4-(1-methylethyl)benzene]ruthenium
  • Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
    cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
  • Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%
  • Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
  • Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II)
  • Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(S,S)-Tsdpen](p-cyMene)
  • [RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)]
  • Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(S,S)-Tsdpen](p-cyMene)
  • RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore
  • [(η-6-CyMene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaMinato]rutheniuM] chloride]
  • Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene)
  • RuCl(p-cymene)[(S,S)-Ts-DPEN] Chloro{[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • [(1S,2S)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide,chlororuthenium(1+),1-methyl-4-propan-2-ylbenzene
  • [N-[(1S,2S)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-
  • Ruthenium,[N-[(1S,2S)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-
  • (S,S)-N-(p-ToL
  • ethanediamine(chL
  • oro)(p-cymene)ruthenium(II)
  • )-1,2-diphenyL
  • Chloro(p-cymene)[(S,S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
  • [(S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II)
  • (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) ISO 9001:2015 REACH
  • (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro...
  • [(1S,2S)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide
  • RuCl(p-cymene)[(S,S)-Ts-DPEN]
  • RuCl[(S,S)- Tsdpen](p-cyMene)
  • [((S,S)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II)
  • RuCl[(S,S)-Tsdpen](p-cymene)/Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
  • ((S,S)-2-Amino-1,2-Diphenylethyl)[(4-Tolyl)Sulfonyl]Amido](P-Cymene)Ruthenium (II)Chloride
  • N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium (ACI)
  • 192139-90-5
  • C32H44ClN2O2RuS
  • organometallic complex
  • Ru
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