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ChemicalBook >> CAS DataBase List >> Tributylphosphine

Tributylphosphine

Tributylphosphine price.
  • $18.33 - $1005.43
  • Product name: Tributylphosphine
  • CAS: 998-40-3
  • MF: C12H27P
  • MW: 202.32
  • EINECS:213-651-2
  • MDL Number:MFCD00009462
  • Synonyms:TRI-N-BUTYLPHOSPHINE (10 WT% IN HEXANE);TRIBUTYL PHOSPHINE (TBP);Tri-n-butylphosphine,99%;Tri-n-butylphosphine,99%(10wt%inhexane);Tri-n-butylphosphine,min.93%;cytop 340;tributylphosphine solution;TRI-N-BUTYLPHOSPHINE OR PHOSPHINE, TRIBUTYL
33 prices
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Brand
  • Acrotein
  • AHH
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
  • TRC
Package
  • 100mg
  • 500mg
  • 1G
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  • 2.500g
  • 5G
  • 5ml
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  • 10vials
  • 25g
  • 25ml
  • 100g
  • 250g
  • 1Kg
  • *2x500g
  • 50g
  • 100ml
  • 500ml
  • ManufacturerAcrotein
  • Product numberAC-2969
  • Product descriptionTri-n-butylphosphine 97%
  • Packaging25g
  • Price$18.33
  • Updated2021-12-16
  • Buy
  • ManufacturerAcrotein
  • Product numberAC-2969
  • Product descriptionTri-n-butylphosphine 97%
  • Packaging100g
  • Price$47.67
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMB-18106
  • Product descriptionTRI-N-BUTYLPHOSPHINE 97%
  • Packaging1Kg
  • Price$358
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12649
  • Product descriptionTri-n-butylphosphine 95%
  • Packaging25ml
  • Price$41.4
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number014114
  • Product descriptionTri-n-butylphosphine 94%
  • Packaging50g
  • Price$44.4
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12649
  • Product descriptionTri-n-butylphosphine 95%
  • Packaging100ml
  • Price$98.2
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number014114
  • Product descriptionTri-n-butylphosphine 94%
  • Packaging250g
  • Price$179
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12649
  • Product descriptionTri-n-butylphosphine 95%
  • Packaging500ml
  • Price$323
  • Updated2023-06-20
  • Buy
  • ManufacturerAlfa Aesar
  • Product number014114
  • Product descriptionTri-n-butylphosphine 94%
  • Packaging*2x500g
  • Price$576
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0092269
  • Product descriptionTRI-N-BUTYLPHOSPHINE 95.00%
  • Packaging1G
  • Price$648.81
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0092269
  • Product descriptionTRI-N-BUTYLPHOSPHINE 95.00%
  • Packaging2.5G
  • Price$852.21
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0092269
  • Product descriptionTRI-N-BUTYLPHOSPHINE 95.00%
  • Packaging5G
  • Price$1005.43
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number133930
  • Product descriptionTributylphosphane 95%+
  • Packaging100mg
  • Price$56
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number133930
  • Product descriptionTributylphosphane 95%+
  • Packaging500mg
  • Price$103
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number133930
  • Product descriptionTributylphosphane 95%+
  • Packaging2.500g
  • Price$283
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number90827
  • Product descriptionTributylphosphine ≥93.5% (Tri-
  • Packaging25ml
  • Price$79.5
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AC-2969 Tri-n-butylphosphine 97% 25g $18.33 2021-12-16 Buy
Acrotein AC-2969 Tri-n-butylphosphine 97% 100g $47.67 2021-12-16 Buy
AHH MB-18106 TRI-N-BUTYLPHOSPHINE 97% 1Kg $358 2021-12-16 Buy
Alfa Aesar A12649 Tri-n-butylphosphine 95% 25ml $41.4 2023-06-20 Buy
Alfa Aesar 014114 Tri-n-butylphosphine 94% 50g $44.4 2024-03-01 Buy
Alfa Aesar A12649 Tri-n-butylphosphine 95% 100ml $98.2 2023-06-20 Buy
Alfa Aesar 014114 Tri-n-butylphosphine 94% 250g $179 2024-03-01 Buy
Alfa Aesar A12649 Tri-n-butylphosphine 95% 500ml $323 2023-06-20 Buy
Alfa Aesar 014114 Tri-n-butylphosphine 94% *2x500g $576 2024-03-01 Buy
American Custom Chemicals Corporation CHM0092269 TRI-N-BUTYLPHOSPHINE 95.00% 1G $648.81 2021-12-16 Buy
American Custom Chemicals Corporation CHM0092269 TRI-N-BUTYLPHOSPHINE 95.00% 2.5G $852.21 2021-12-16 Buy
American Custom Chemicals Corporation CHM0092269 TRI-N-BUTYLPHOSPHINE 95.00% 5G $1005.43 2021-12-16 Buy
Matrix Scientific 133930 Tributylphosphane 95%+ 100mg $56 2021-12-16 Buy
Matrix Scientific 133930 Tributylphosphane 95%+ 500mg $103 2021-12-16 Buy
Matrix Scientific 133930 Tributylphosphane 95%+ 2.500g $283 2021-12-16 Buy
Sigma-Aldrich 90827 Tributylphosphine ≥93.5% (Tri- 25ml $79.5 2024-03-01 Buy

Properties

Melting point :-65 °C
Boiling point :150 °C50 mm Hg(lit.)
Density :0.81 g/mL at 25 °C(lit.)
vapor density :9 (vs air)
vapor pressure :1.9Pa at 20℃
refractive index :n20/D 1.462(lit.)
Flash point :99 °F
storage temp. :2-8°C
form :liquid
Specific Gravity :0.820 (20/4℃)
color :Clear colorless to pale yellow
Water Solubility :insoluble
Sensitive :Moisture Sensitive/Air Sensitive
BRN :1738261
Stability :Stable, but pyrophoric - spontaneously inflammable in air. Incompatible with oxidizing agents. Moisture sensitive.
InChIKey :TUQOTMZNTHZOKS-UHFFFAOYSA-N
CAS DataBase Reference :998-40-3(CAS DataBase Reference)
NIST Chemistry Reference :Phosphine, tributyl-(998-40-3)
EPA Substance Registry System :Phosphine, tributyl- (998-40-3)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H251 Self-heating; may catch fire Self-heating substances and mixtures Category 1 Danger GHS hazard pictograms
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P235 Keep cool.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Tri-n-butylphosphine is used as a catalyst modifier in the cobalt-catalyzed hydroformylation of alkenes for industrial use. It is also used as a strong reducing agent and polymerization cross-linking catalyst. It is a used as an intermediate for phase transfer catalysts. Used with platinum (II) or (IV) in an intermolecular hydroamination of inactivated alkenes. It is used as 1,4-addition catalyst; used with disulfides for the thioetherification of alcohols; acylation catalyst; used to prepare active esters.

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