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ChemicalBook >> CAS DataBase List >> Methyl nitroacetate

Methyl nitroacetate

Methyl nitroacetate price.
  • $11 - $1110.88
  • Product name: Methyl nitroacetate
  • CAS: 2483-57-0
  • MF: C3H5NO4
  • MW: 119.08
  • EINECS:219-622-0
  • MDL Number:MFCD00075480
  • Synonyms:NITROACETIC ACID METHYL ESTER;Methyl a-nitroacetate;methyl2-nitroacetate ;nitro-aceticacimethylester ;METHYL ALFA NITROACETATE;METHYL NITROACETATE;Methylnitroacetate,98%;Methyl nitrozcetate
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  • AK Scientific
  • Alfa Aesar
  • Ambeed
  • American Custom Chemicals Corporation
  • Apolloscientific
  • ChemScene
  • Matrix Scientific
  • Medical Isotopes, Inc.
  • Sigma-Aldrich
  • SynQuest Laboratories
  • TCI Chemical
  • TRC
Package
  • 1g
  • 2g
  • 5g
  • 10g
  • 25g
  • 100g
  • ManufacturerAK Scientific
  • Product numberJ93277
  • Product descriptionMethyl nitroacetate
  • Packaging1g
  • Price$25
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ93277
  • Product descriptionMethyl nitroacetate
  • Packaging5g
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ20054
  • Product descriptionMethyl nitroacetate
  • Packaging1g
  • Price$104
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberL18950
  • Product descriptionMethyl nitroacetate, 98%
  • Packaging2g
  • Price$68.65
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product numberL18950
  • Product descriptionMethyl nitroacetate, 98%
  • Packaging10g
  • Price$255.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAmbeed
  • Product numberA1467780
  • Product descriptionMethyl2-nitroacetate 98%
  • Packaging1g
  • Price$11
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA1467780
  • Product descriptionMethyl2-nitroacetate 98%
  • Packaging5g
  • Price$41
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA104731
  • Product descriptionMethyl2-nitroacetate 96%
  • Packaging10g
  • Price$81
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA1467780
  • Product descriptionMethyl2-nitroacetate 98%
  • Packaging25g
  • Price$190
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA1467780
  • Product descriptionMethyl2-nitroacetate 98%
  • Packaging100g
  • Price$684
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0014554
  • Product descriptionMETHYL NITROACETATE 95.00%
  • Packaging1G
  • Price$718.91
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0014554
  • Product descriptionMETHYL NITROACETATE 95.00%
  • Packaging5G
  • Price$1110.88
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR2038
  • Product descriptionMethyl nitroacetate 99%
  • Packaging5g
  • Price$77
  • Updated2021-12-16
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  • ManufacturerChemScene
  • Product numberCS-0130670
  • Product descriptionMethyl2-nitroacetate
  • Packaging25g
  • Price$230
  • Updated2021-12-16
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  • ManufacturerChemScene
  • Product numberCS-0130670
  • Product descriptionMethyl2-nitroacetate
  • Packaging100g
  • Price$742
  • Updated2021-12-16
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  • ManufacturerMatrix Scientific
  • Product number099836
  • Product descriptionMethyl 2-nitroacetate 95+%
  • Packaging1g
  • Price$53
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific J93277 Methyl nitroacetate 1g $25 2021-12-16 Buy
AK Scientific J93277 Methyl nitroacetate 5g $75 2021-12-16 Buy
AK Scientific J20054 Methyl nitroacetate 1g $104 2021-12-16 Buy
Alfa Aesar L18950 Methyl nitroacetate, 98% 2g $68.65 2024-03-01 Buy
Alfa Aesar L18950 Methyl nitroacetate, 98% 10g $255.65 2024-03-01 Buy
Ambeed A1467780 Methyl2-nitroacetate 98% 1g $11 2021-12-16 Buy
Ambeed A1467780 Methyl2-nitroacetate 98% 5g $41 2021-12-16 Buy
Ambeed A104731 Methyl2-nitroacetate 96% 10g $81 2021-12-16 Buy
Ambeed A1467780 Methyl2-nitroacetate 98% 25g $190 2021-12-16 Buy
Ambeed A1467780 Methyl2-nitroacetate 98% 100g $684 2021-12-16 Buy
American Custom Chemicals Corporation CHM0014554 METHYL NITROACETATE 95.00% 1G $718.91 2021-12-16 Buy
American Custom Chemicals Corporation CHM0014554 METHYL NITROACETATE 95.00% 5G $1110.88 2021-12-16 Buy
Apolloscientific OR2038 Methyl nitroacetate 99% 5g $77 2021-12-16 Buy
ChemScene CS-0130670 Methyl2-nitroacetate 25g $230 2021-12-16 Buy
ChemScene CS-0130670 Methyl2-nitroacetate 100g $742 2021-12-16 Buy
Matrix Scientific 099836 Methyl 2-nitroacetate 95+% 1g $53 2021-12-16 Buy

Properties

Boiling point :195-198 °C (lit.)
Density :1.294 g/mL at 25 °C (lit.)
refractive index :n20/D 1.425(lit.)
Flash point :221 °F
storage temp. :Keep in dark place,Sealed in dry,Room Temperature
solubility :Miscible with ethanol, ether and most organic solvents.
pka :5.73±0.29(Predicted)
form :clear liquid
color :Colorless to Light yellow
Sensitive :Light Sensitive
BRN :1758670
InChI :InChI=1S/C3H5NO4/c1-8-3(5)2-4(6)7/h2H2,1H3
InChIKey :ALBSWLMUHHZLLR-UHFFFAOYSA-N
SMILES :C(OC)(=O)C[N+]([O-])=O
CAS DataBase Reference :2483-57-0(CAS DataBase Reference)
NIST Chemistry Reference :Acetic acid, nitro-, methyl ester(2483-57-0)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

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