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ChemicalBook >> CAS DataBase List >> Methyllithium

Methyllithium

Methyllithium price.
  • $52.1 - $5650
  • Product name: Methyllithium
  • CAS: 917-54-4
  • MF: CH3Li
  • MW: 21.98
  • EINECS:213-026-4
  • MDL Number:MFCD00008253
  • Synonyms:METHYLLITHIUM;LITHIUM METHYL;MethyllithiumcomplexedwithlithiumbromideinethyletherMc;METHYLLITHIUM SOLUTION, ~5 % IN DIETHYL ETHER;METHYLLITHIUM SOL., ~1 M IN CUMENE/THF;methyl-lithiu ;MethyllithiuM, 3% solution in 2-MeTHF/cuMene, AcroSeal;MethyllithiuM in ether 1.6M
20 prices
Selected condition:
Brand
  • Alfa Aesar
  • Sigma-Aldrich
  • Strem Chemicals
  • TRC
Package
  • 0.25mole
  • 25ml
  • 1mole
  • 50ml
  • 100ml
  • 4x25ml
  • 250ml
  • 4x100ml
  • 800ml
  • 1L
  • 8l
  • 18L
  • ManufacturerAlfa Aesar
  • Product number042992
  • Product descriptionMethyllithium, 1-2M in ether packaged under Argon in resealable ChemSeal? bottles
  • Packaging25ml
  • Price$52.1
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number042992
  • Product descriptionMethyllithium, 1-2M in ether packaged under Argon in resealable ChemSeal? bottles
  • Packaging100ml
  • Price$126
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number197343
  • Product descriptionMethyllithium solution 1.6M in diethyl ether
  • Packaging50ml
  • Price$57.6
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number197343
  • Product descriptionMethyllithium solution 1.6M in diethyl ether
  • Packaging4x25ml
  • Price$71.3
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number197343
  • Product descriptionMethyllithium solution 1.6M in diethyl ether
  • Packaging100ml
  • Price$74.9
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number514330
  • Product descriptionMethyllithium solution 3.1 M in diethoxymethane
  • Packaging4x25ml
  • Price$93.4
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number186201
  • Product descriptionMethyllithium lithium bromide complex solution 1.5?M in diethyl ether
  • Packaging100mL
  • Price$97.3
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number514330
  • Product descriptionMethyllithium solution 3.1 M in diethoxymethane
  • Packaging100ml
  • Price$98.3
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number186201
  • Product descriptionMethyllithium lithium bromide complex solution 1.5?M in diethyl ether
  • Packaging1L
  • Price$620
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number197343
  • Product descriptionMethyllithium solution 1.6M in diethyl ether
  • Packaging8l
  • Price$1960
  • Updated2023-06-20
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number186201
  • Product descriptionMethyllithium lithium bromide complex solution 1.5?M in diethyl ether
  • Packaging18L
  • Price$5650
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number186201
  • Product descriptionMethyllithium lithium bromide complex solution 1.5?M in diethyl ether
  • Packaging4x25ml
  • Price$125
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number197343
  • Product descriptionMethyllithium solution 1.6M in diethyl ether
  • Packaging800ml
  • Price$263
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number197343
  • Product descriptionMethyllithium solution 1.6M in diethyl ether
  • Packaging4x100ml
  • Price$292
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number197343
  • Product descriptionMethyllithium solution 1.6M in diethyl ether
  • Packaging1l
  • Price$309
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number514330
  • Product descriptionMethyllithium solution 3.1 M in diethoxymethane
  • Packaging1l
  • Price$558
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 042992 Methyllithium, 1-2M in ether packaged under Argon in resealable ChemSeal? bottles 25ml $52.1 2021-12-16 Buy
Alfa Aesar 042992 Methyllithium, 1-2M in ether packaged under Argon in resealable ChemSeal? bottles 100ml $126 2021-12-16 Buy
Sigma-Aldrich 197343 Methyllithium solution 1.6M in diethyl ether 50ml $57.6 2024-03-01 Buy
Sigma-Aldrich 197343 Methyllithium solution 1.6M in diethyl ether 4x25ml $71.3 2024-03-01 Buy
Sigma-Aldrich 197343 Methyllithium solution 1.6M in diethyl ether 100ml $74.9 2024-03-01 Buy
Sigma-Aldrich 514330 Methyllithium solution 3.1 M in diethoxymethane 4x25ml $93.4 2024-03-01 Buy
Sigma-Aldrich 186201 Methyllithium lithium bromide complex solution 1.5?M in diethyl ether 100mL $97.3 2024-03-01 Buy
Sigma-Aldrich 514330 Methyllithium solution 3.1 M in diethoxymethane 100ml $98.3 2024-03-01 Buy
Sigma-Aldrich 186201 Methyllithium lithium bromide complex solution 1.5?M in diethyl ether 1L $620 2024-03-01 Buy
Sigma-Aldrich 197343 Methyllithium solution 1.6M in diethyl ether 8l $1960 2023-06-20 Buy
Sigma-Aldrich 186201 Methyllithium lithium bromide complex solution 1.5?M in diethyl ether 18L $5650 2024-03-01 Buy
Sigma-Aldrich 186201 Methyllithium lithium bromide complex solution 1.5?M in diethyl ether 4x25ml $125 2024-03-01 Buy
Sigma-Aldrich 197343 Methyllithium solution 1.6M in diethyl ether 800ml $263 2024-03-01 Buy
Sigma-Aldrich 197343 Methyllithium solution 1.6M in diethyl ether 4x100ml $292 2024-03-01 Buy
Sigma-Aldrich 197343 Methyllithium solution 1.6M in diethyl ether 1l $309 2024-03-01 Buy
Sigma-Aldrich 514330 Methyllithium solution 3.1 M in diethoxymethane 1l $558 2024-03-01 Buy

Properties

Melting point :70-71℃
Boiling point :88℃
Density :0.85 g/mL at 20 °C
vapor density :3 (vs air)
Flash point :5 °F
storage temp. :2-8°C
form :Solution
color :Colorless to yellow
Specific Gravity :0.83
Water Solubility :Reacts with water.
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required
BRN :3587162
Exposure limits :ACGIH: TWA 400 ppm; STEL 500 ppm
OSHA: TWA 400 ppm(1200 mg/m3)
NIOSH: IDLH 1900 ppm CAS DataBase Reference :917-54-4(CAS DataBase Reference)
EPA Substance Registry System :Lithium, methyl- (917-54-4)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H252 Self-heating in large quantities; may catch fire Self-heating substances and mixtures Category 2 Warning P235+P410, P280, P407, P413, P420
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H303 May be harmfulif swallowed Acute toxicity,oral Category 5 P312
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger GHS hazard pictograms P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222 Do not allow contact with air.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P405 Store locked up.
P422 Store contents under …

Description

Used as a solution in ethers, is a reagent in organic synthesis as well as organometallic chemistry. Also used in Grignard-type reactions.

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