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ChemicalBook >> CAS DataBase List >> Lithium diisopropylamide

Lithium diisopropylamide

Lithium diisopropylamide price.
  • $60 - $7033.95
  • Product name: Lithium diisopropylamide
  • CAS: 4111-54-0
  • MF: C6H16LiN
  • MW: 109.14
  • EINECS:223-893-0
  • MDL Number:MFCD00064449
  • Synonyms:LITHIUM DIISOPROPYLAMIDE THF COMPLEX;LITHIUM DIISOPROPYLAMIDE;LDA THF COMPLEX;DIISOPROPYLAMINOLITHIUM;Lithium diisopropylamide solution;n-(1-methylethyl)-2-propanaminlithiumsalt ;Lithium diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene;LITHIUMDIISOPROPYLAMIDE,2MSOLUTIONINTETRAHYDROFURAN/HEPTANE/ETHYLBENZENE
17 prices
Selected condition：
Brand
  • AHH
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
  • TCI Chemical
  • Usbiological
Package
  • 25g
  • 50g
  • 75g
  • 100g
  • 100ml
  • 4x25ml
  • 250G
  • 4x100ml
  • 500ml
  • 800ml
  • 1KG
  • ManufacturerAHH
  • Product numberMT-09988
  • Product descriptionDiisopropylaminolithium 97%
  • Packaging100g
  • Price$350
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004402
  • Product descriptionLITHIUM DIISOPROPYLAMIDE 95.00%
  • Packaging100G
  • Price$2486.14
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004402
  • Product descriptionLITHIUM DIISOPROPYLAMIDE 95.00%
  • Packaging250G
  • Price$4365.9
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004402
  • Product descriptionLITHIUM DIISOPROPYLAMIDE 95.00%
  • Packaging1KG
  • Price$7033.95
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number774766
  • Product descriptionLithium diisopropylamide solution 1.0 M in THF/hexanes
  • Packaging4x25ml
  • Price$62.2
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number296961
  • Product descriptionLithium diisopropylamide 10 wt. % suspension in hexanes
  • Packaging75g
  • Price$63
  • Updated2022-05-15
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number774766
  • Product descriptionLithium diisopropylamide solution 1.0 M in THF/hexanes
  • Packaging100ml
  • Price$65.5
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0 M in THF/heptane/ethylbenzene
  • Packaging4x25ml
  • Price$65.9
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0 M in THF/heptane/ethylbenzene
  • Packaging100ml
  • Price$69.4
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number774766
  • Product descriptionLithium diisopropylamide solution 1.0 M in THF/hexanes
  • Packaging500ml
  • Price$222
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0 M in THF/heptane/ethylbenzene
  • Packaging4x100ml
  • Price$251
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number361798
  • Product descriptionLithium diisopropylamide solution 2.0 M in THF/heptane/ethylbenzene
  • Packaging800ml
  • Price$253
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number246611
  • Product descriptionLithium diisopropylamide 97%
  • Packaging25g
  • Price$415
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number246611
  • Product descriptionLithium diisopropylamide 97%
  • Packaging100g
  • Price$895
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberL0171
  • Product descriptionLithium Diisopropylamide (ca. 20% in Tetrahydrofuran/Ethylbenzene/Heptane, ca. 1.5mol/L)
  • Packaging100mL
  • Price$60
  • Updated2021-12-16
  • Buy
  • ManufacturerTCI Chemical
  • Product numberL0171
  • Product descriptionLithium Diisopropylamide (ca. 20% in Tetrahydrofuran/Ethylbenzene/Heptane, ca. 1.5mol/L)
  • Packaging500mL
  • Price$167
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-09988 Diisopropylaminolithium 97% 100g $350 2021-12-16 Buy
American Custom Chemicals Corporation ING0004402 LITHIUM DIISOPROPYLAMIDE 95.00% 100G $2486.14 2021-12-16 Buy
American Custom Chemicals Corporation ING0004402 LITHIUM DIISOPROPYLAMIDE 95.00% 250G $4365.9 2021-12-16 Buy
American Custom Chemicals Corporation ING0004402 LITHIUM DIISOPROPYLAMIDE 95.00% 1KG $7033.95 2021-12-16 Buy
Sigma-Aldrich 774766 Lithium diisopropylamide solution 1.0 M in THF/hexanes 4x25ml $62.2 2024-03-01 Buy
Sigma-Aldrich 296961 Lithium diisopropylamide 10 wt. % suspension in hexanes 75g $63 2022-05-15 Buy
Sigma-Aldrich 774766 Lithium diisopropylamide solution 1.0 M in THF/hexanes 100ml $65.5 2024-03-01 Buy
Sigma-Aldrich 361798 Lithium diisopropylamide solution 2.0 M in THF/heptane/ethylbenzene 4x25ml $65.9 2024-03-01 Buy
Sigma-Aldrich 361798 Lithium diisopropylamide solution 2.0 M in THF/heptane/ethylbenzene 100ml $69.4 2024-03-01 Buy
Sigma-Aldrich 774766 Lithium diisopropylamide solution 1.0 M in THF/hexanes 500ml $222 2024-03-01 Buy
Sigma-Aldrich 361798 Lithium diisopropylamide solution 2.0 M in THF/heptane/ethylbenzene 4x100ml $251 2024-03-01 Buy
Sigma-Aldrich 361798 Lithium diisopropylamide solution 2.0 M in THF/heptane/ethylbenzene 800ml $253 2024-03-01 Buy
Sigma-Aldrich 246611 Lithium diisopropylamide 97% 25g $415 2024-03-01 Buy
Sigma-Aldrich 246611 Lithium diisopropylamide 97% 100g $895 2024-03-01 Buy
TCI Chemical L0171 Lithium Diisopropylamide (ca. 20% in Tetrahydrofuran/Ethylbenzene/Heptane, ca. 1.5mol/L) 100mL $60 2021-12-16 Buy
TCI Chemical L0171 Lithium Diisopropylamide (ca. 20% in Tetrahydrofuran/Ethylbenzene/Heptane, ca. 1.5mol/L) 500mL $167 2021-12-16 Buy

Properties

Melting point :decomposes [MER06]
Boiling point :65 °C
Density :0.864 g/mL at 25 °C (lit.)
vapor density :>1 (vs air)
Flash point :91 °F
storage temp. :2-8°C
solubility :soluble in ethyl ether; insoluble in hydrocarbon solvents
form :liquid
color :brown
Water Solubility :decomposes
Sensitive :Air & Moisture Sensitive
Merck :14,3196
BRN :3655042
CAS DataBase Reference :4111-54-0(CAS DataBase Reference)
EPA Substance Registry System :2-Propanamine, N-(1-methylethyl)-, lithium salt (4111-54-0)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P231+P232 Handle under inert gas. Protect from moisture.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.

Description

Titanium-ate enolates prepared from ketones by Ti(OiPr)4and LDA underwent efficient radical trifluoromethylation providing trifluoromethyl ketones in good yield.Used in directedortho-lithiation of arylsulfonyloxazolidinones to prepareN-substituted saccharin analogs.

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