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ChemicalBook >> CAS DataBase List >> (S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate

(S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate

$68 - $2599.8
Product name: (S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate
CAS: 874948-63-7
MF: C50H57O4P
MW: 752.96
EINECS:
MDL Number:MFCD10567009
Synonyms:(S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate;(S)-TRIP;(S)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate >=97.5% (HPLC);(S)-3,3'-Bis(2,4,6-trisopropylphenyl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate;(S)-3,3'-Bis(2,4,6-triIsopropylphenyl)-1,1'-binapthyl-2,2'-diylhydrogenphosphate;(11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide;(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide;(S)-3,3'-Bis(2,4,6-triisopropylphenyl)-1,1'-binaphthyl-2,2'- diyl Hydrogen Phosphate,99%e.e.

Price23 Properties Safety Information Description

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Brand

AK Scientific
Alichem
Ambeed
ChemScene
Crysdot
Matrix Scientific
Sigma-Aldrich
Strem Chemicals
SynQuest Laboratories

Package

25mg
100mg
250mg
500mg
1g
5g
10g

ManufacturerAK Scientific
Product number2222AQ
Product description(S)-TRIP
Packaging100mg
Price$484.4
Updated2021-12-16
Buy

ManufacturerAlichem
Product number874948637
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
Packaging100mg
Price$631.38
Updated2021-12-16
Buy

ManufacturerAlichem
Product number874948637
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
Packaging250mg
Price$960.3
Updated2021-12-16
Buy

ManufacturerAlichem
Product number874948637
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide
Packaging1g
Price$2599.8
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA1324845
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
Packaging100mg
Price$68
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA1324845
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
Packaging250mg
Price$128
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA1324845
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
Packaging1g
Price$428
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA1324845
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
Packaging5g
Price$1280
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA1324845
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee
Packaging10g
Price$1964
Updated2021-12-16
Buy

ManufacturerChemScene
Product numberCS-W020708
Product description(S)-TRIP ≥98.0%
Packaging250mg
Price$128
Updated2021-12-16
Buy

ManufacturerChemScene
Product numberCS-W020708
Product description(S)-TRIP ≥98.0%
Packaging1g
Price$428
Updated2021-12-16
Buy

ManufacturerChemScene
Product numberCS-W020708
Product description(S)-TRIP ≥98.0%
Packaging5g
Price$1280
Updated2021-12-16
Buy

ManufacturerCrysdot
Product numberCD51000219
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
Packaging25mg
Price$307
Updated2021-12-16
Buy

ManufacturerCrysdot
Product numberCD51000219
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
Packaging100mg
Price$613
Updated2021-12-16
Buy

ManufacturerCrysdot
Product numberCD51000219
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
Packaging250mg
Price$980
Updated2021-12-16
Buy

ManufacturerCrysdot
Product numberCD51000219
Product description(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%
Packaging1g
Price$2452
Updated2021-12-16
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
AK Scientific	2222AQ	(S)-TRIP	100mg	$484.4	2021-12-16	Buy
Alichem	874948637	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide	100mg	$631.38	2021-12-16	Buy
Alichem	874948637	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide	250mg	$960.3	2021-12-16	Buy
Alichem	874948637	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide	1g	$2599.8	2021-12-16	Buy
Ambeed	A1324845	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee	100mg	$68	2021-12-16	Buy
Ambeed	A1324845	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee	250mg	$128	2021-12-16	Buy
Ambeed	A1324845	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee	1g	$428	2021-12-16	Buy
Ambeed	A1324845	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee	5g	$1280	2021-12-16	Buy
Ambeed	A1324845	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 98%+99%ee	10g	$1964	2021-12-16	Buy
ChemScene	CS-W020708	(S)-TRIP ≥98.0%	250mg	$128	2021-12-16	Buy
ChemScene	CS-W020708	(S)-TRIP ≥98.0%	1g	$428	2021-12-16	Buy
ChemScene	CS-W020708	(S)-TRIP ≥98.0%	5g	$1280	2021-12-16	Buy
Crysdot	CD51000219	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%	25mg	$307	2021-12-16	Buy
Crysdot	CD51000219	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%	100mg	$613	2021-12-16	Buy
Crysdot	CD51000219	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%	250mg	$980	2021-12-16	Buy
Crysdot	CD51000219	(11bS)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine4-oxide 95+%	1g	$2452	2021-12-16	Buy

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Properties

Boiling point :814.2±75.0 °C(Predicted)
Density :1.17±0.1 g/cm3(Predicted)
storage temp. :Inert atmosphere,Room Temperature
pka :1.12±0.20(Predicted)
form :Powder
color :white to light-yellow

Safety Information

Symbol(GHS):

Signal word:

Warning

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	Pictogram	P-Codes

Precautionary statements:

P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P271	Use only outdoors or in a well-ventilated area.

Description

Versatile organocatalyst. Uses include asymmetric reductive amination, enantioselective Diels-Alder reactions and asymmetric counteranion-directed catalysis (ACDC). Can be used in cooperation with chiral iridium complexes to catalyze greener asymmetric reductive amination using hydrogen gas.

Metal-Br?nsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

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(S)-TRIP, (11bS)-4-Hydroxy-2,6-bis[2,4,6-tris(1-methylethyl)phenyl]dinaphtho[2,1-d:1μ,2μ-f]-1,3,2-dioxaphosphepin 4-oxide, (S)-3,3μ-Bis(2,4,6-triisopropylphenyl)-1,1μ-bi-2-naphthol cyclic monophosphate

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Safety Information

Description

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