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ChemicalBook >> CAS DataBase List >> Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) price.
  • $19.74 - $925
  • Product name: Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • CAS: 325146-81-4
  • MF: C48H40O4P2Ru
  • MW: 843.86
  • EINECS:
  • MDL Number:MFCD09753020
  • Synonyms:Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II);(R)-Ru(OAc)2(BINAP),Diacetato[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′binaphthyl]ruthenium(II);Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap];RU(OAC)2[(R)-BINAP];Ru(OAc)2[(R)-binap];-binaphthyl]ruthenium(II),Ru(OAc)2[(R)-binap].;(OC-6-22)-Bis(acetato-κO,κO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[diphenylphosphine-κP]]ruthenium;(R)-Ru(OAc)2(BINAP),Diacetato[(R)-(+)-2,2bis(diphenylphosphino)-1,1inaphthyl]ruthenium(II)
18 prices
Selected condition：
Brand
  • Ambeed
  • American Custom Chemicals Corporation
  • Biosynth Carbosynth
  • Chemenu
  • Crysdot
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
Package
  • 5MG
  • 100mg
  • 200mg
  • 250mg
  • 500mg
  • 1g
  • 2g
  • 5g
  • ManufacturerAmbeed
  • Product numberA118464
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98%
  • Packaging250mg
  • Price$33
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA118464
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98%
  • Packaging1g
  • Price$111
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA118464
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98%
  • Packaging5g
  • Price$432
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0013132
  • Product descriptionDIACETATO-[(R)-(+)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM-(II) 95.00%
  • Packaging5MG
  • Price$503.91
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD162446
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • Packaging250mg
  • Price$130
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD162446
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • Packaging500mg
  • Price$200
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD162446
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • Packaging1g
  • Price$310
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD162446
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • Packaging2g
  • Price$500
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFD162446
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • Packaging5G
  • Price$925
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM102910
  • Product descriptionDiacetato[(R)-2,2''-bis(diphenylphosphino)-1,1''-binaphthyl]ruthenium(II) 95%
  • Packaging1g
  • Price$280
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD52000628
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 95+%
  • Packaging1g
  • Price$295
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number692220
  • Product description(R)-Ru(OAc)2(BINAP)
  • Packaging500mg
  • Price$83.4
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number692220
  • Product description(R)-Ru(OAc)2(BINAP)
  • Packaging100mg
  • Price$19.74
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0152
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]
  • Packaging250mg
  • Price$53
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0152
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]
  • Packaging1g
  • Price$158
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0152
  • Product descriptionDiacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]
  • Packaging5g
  • Price$379
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A118464 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98% 250mg $33 2021-12-16 Buy
Ambeed A118464 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98% 1g $111 2021-12-16 Buy
Ambeed A118464 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 98% 5g $432 2021-12-16 Buy
American Custom Chemicals Corporation ING0013132 DIACETATO-[(R)-(+)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM-(II) 95.00% 5MG $503.91 2021-12-16 Buy
Biosynth Carbosynth FD162446 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 250mg $130 2021-12-16 Buy
Biosynth Carbosynth FD162446 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 500mg $200 2021-12-16 Buy
Biosynth Carbosynth FD162446 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 1g $310 2021-12-16 Buy
Biosynth Carbosynth FD162446 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 2g $500 2021-12-16 Buy
Biosynth Carbosynth FD162446 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 5G $925 2021-12-16 Buy
Chemenu CM102910 Diacetato[(R)-2,2''-bis(diphenylphosphino)-1,1''-binaphthyl]ruthenium(II) 95% 1g $280 2021-12-16 Buy
Crysdot CD52000628 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) 95+% 1g $295 2021-12-16 Buy
Sigma-Aldrich 692220 (R)-Ru(OAc)2(BINAP) 500mg $83.4 2024-03-01 Buy
Sigma-Aldrich 692220 (R)-Ru(OAc)2(BINAP) 100mg $19.74 2024-03-01 Buy
Strem Chemicals 44-0152 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap] 250mg $53 2024-03-01 Buy
Strem Chemicals 44-0152 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap] 1g $158 2024-03-01 Buy
Strem Chemicals 44-0152 Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap] 5g $379 2024-03-01 Buy

Properties

Melting point :>100°C
storage temp. :2-8°C
form :Powder
color :ocher to green
Sensitive :air sensitive
InChIKey :XANQJWCSQJDBEA-UHFFFAOYSA-N
SMILES :CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2=CC=C4C=CC=CC4=C2C2=C4C=CC=CC4=CC=C2P3(C2C=CC=CC=2)C2C=CC=CC=2)[O-]1

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P337+P313 IF eye irritation persists: Get medical advice/attention.

Description

(R)-Ru(OAc)2(BINAP) may be used as a catalyst for the asymmetric hydrogenation of 1,1′-disubstituted olefins, such as 1-methyleneindan and 1-methylenetetralins.It can also catalyze the hydrogenation of 2-(trifluoromethyl)acrylic acid to form optically active 2-(trifluoromethyl)propionic acid.

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