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ChemicalBook >> CAS DataBase List >> Methyl (triphenylphosphoranylidene)acetate

Methyl (triphenylphosphoranylidene)acetate

Methyl (triphenylphosphoranylidene)acetate price.
  • $5 - $5058.9
  • Product name: Methyl (triphenylphosphoranylidene)acetate
  • CAS: 2605-67-6
  • MF: C21H19O2P
  • MW: 334.35
  • EINECS:220-018-4
  • MDL Number:MFCD00008455
  • Synonyms:(TRIPHENYLPHOSPHORANYLIDENE)ACETIC ACID METHYL ESTER;AURORA KA-874;(CARBOMETHOXYMETHYLENE)TRIPHENYLPHOSPHORANE;METHYL (TRIPHENYLPHOSPHORANYLIDENE)ACETATE;(2-METHOXY-2-OXOETHYLIDENE)TRIPHENYLPHOSPHORANE;ACETIC ACID, (TRIPHENYLPHOSPHORANYLIDENE)-, METHYL ESTER;Triphenylphosphinideneacetic acid methyl ester;Triphenylphosphoranylideneacetic acid methyl
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  • Acrotein
  • AHH
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  • Chemenu
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  • ManufacturerAcrotein
  • Product numberAC-6537
  • Product descriptionMethyl (triphenylphosphoranylidene)acetate 97%
  • Packaging25g
  • Price$23.83
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMT-04454
  • Product descriptionCarbomethoxymethylenetriphenylphosphorane 98%
  • Packaging500g
  • Price$685
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ90602
  • Product descriptionMethyl (triphenylphosphoranylidene)acetate
  • Packaging500g
  • Price$160
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberI511
  • Product descriptionMethyl (triphenylphosphoranylidene)acetate
  • Packaging1kg
  • Price$361
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA14020
  • Product description(Methoxycarbonylmethylene)triphenylphosphorane, 98%
  • Packaging25g
  • Price$103
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA14020
  • Product description(Methoxycarbonylmethylene)triphenylphosphorane, 98%
  • Packaging100g
  • Price$292
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA14020
  • Product description(Methoxycarbonylmethylene)triphenylphosphorane, 98%
  • Packaging500g
  • Price$1042
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA197326
  • Product descriptionMethyl2-(triphenylphosphoranylidene)acetate 98%
  • Packaging5g
  • Price$5
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA197326
  • Product descriptionMethyl2-(triphenylphosphoranylidene)acetate 98%
  • Packaging10g
  • Price$7
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA197326
  • Product descriptionMethyl2-(triphenylphosphoranylidene)acetate 98%
  • Packaging25g
  • Price$9
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA197326
  • Product descriptionMethyl2-(triphenylphosphoranylidene)acetate 98%
  • Packaging100g
  • Price$32
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA197326
  • Product descriptionMethyl2-(triphenylphosphoranylidene)acetate 98%
  • Packaging500g
  • Price$120
  • Updated2021-12-16
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  • ManufacturerAmbeed
  • Product numberA197326
  • Product descriptionMethyl2-(triphenylphosphoranylidene)acetate 98%
  • Packaging1kg
  • Price$226
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0030406
  • Product descriptionMETHYL (TRIPHENYLPHOSPHORANYLIDENE)ACETATE 95.00%
  • Packaging25G
  • Price$1166.55
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0030406
  • Product descriptionMETHYL (TRIPHENYLPHOSPHORANYLIDENE)ACETATE 95.00%
  • Packaging250G
  • Price$5058.9
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR10660
  • Product descriptionMethyl (triphenylphosphoranylidene)acetate 98%
  • Packaging25g
  • Price$21
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AC-6537 Methyl (triphenylphosphoranylidene)acetate 97% 25g $23.83 2021-12-16 Buy
AHH MT-04454 Carbomethoxymethylenetriphenylphosphorane 98% 500g $685 2021-12-16 Buy
AK Scientific J90602 Methyl (triphenylphosphoranylidene)acetate 500g $160 2021-12-16 Buy
AK Scientific I511 Methyl (triphenylphosphoranylidene)acetate 1kg $361 2021-12-16 Buy
Alfa Aesar A14020 (Methoxycarbonylmethylene)triphenylphosphorane, 98% 25g $103 2024-03-01 Buy
Alfa Aesar A14020 (Methoxycarbonylmethylene)triphenylphosphorane, 98% 100g $292 2024-03-01 Buy
Alfa Aesar A14020 (Methoxycarbonylmethylene)triphenylphosphorane, 98% 500g $1042 2021-12-16 Buy
Ambeed A197326 Methyl2-(triphenylphosphoranylidene)acetate 98% 5g $5 2021-12-16 Buy
Ambeed A197326 Methyl2-(triphenylphosphoranylidene)acetate 98% 10g $7 2021-12-16 Buy
Ambeed A197326 Methyl2-(triphenylphosphoranylidene)acetate 98% 25g $9 2021-12-16 Buy
Ambeed A197326 Methyl2-(triphenylphosphoranylidene)acetate 98% 100g $32 2021-12-16 Buy
Ambeed A197326 Methyl2-(triphenylphosphoranylidene)acetate 98% 500g $120 2021-12-16 Buy
Ambeed A197326 Methyl2-(triphenylphosphoranylidene)acetate 98% 1kg $226 2021-12-16 Buy
American Custom Chemicals Corporation CHM0030406 METHYL (TRIPHENYLPHOSPHORANYLIDENE)ACETATE 95.00% 25G $1166.55 2021-12-16 Buy
American Custom Chemicals Corporation CHM0030406 METHYL (TRIPHENYLPHOSPHORANYLIDENE)ACETATE 95.00% 250G $5058.9 2021-12-16 Buy
Apolloscientific OR10660 Methyl (triphenylphosphoranylidene)acetate 98% 25g $21 2021-12-16 Buy

Properties

Melting point :168-172 °C (lit.)
Boiling point :165~170℃
Density :1.17±0.1 g/cm3(Predicted)
storage temp. :Keep in dark place,Sealed in dry,Room Temperature
solubility :Acetonitrile (Slightly), Chloroform (Slightly)
form :Powder
color :White to off-white
Water Solubility :insoluble
Sensitive :Air Sensitive
BRN :618430
InChIKey :NTNUDYROPUKXNA-UHFFFAOYSA-N
CAS DataBase Reference :2605-67-6(CAS DataBase Reference)
EPA Substance Registry System :Acetic acid, (triphenylphosphoranylidene)-, methyl ester (2605-67-6)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

(Methoxycarbonylmethylene)triphenylphosphorane is used in olefination reactions. Further, it undergoes the Wittig reaction with aldehydes to give substituted methyl acrylates. It is used in the preparation of (triphenylphosphoranylidene)-ketene.

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