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ChemicalBook >> CAS DataBase List >> Diethyl 1,3-acetonedicarboxylate

Diethyl 1,3-acetonedicarboxylate

Diethyl 1,3-acetonedicarboxylate price.
  • $6 - $912.29
  • Product name: Diethyl 1,3-acetonedicarboxylate
  • CAS: 105-50-0
  • MF: C9H14O5
  • MW: 202.2
  • EINECS:203-302-2
  • MDL Number:MFCD00009200
  • Synonyms:Diethyl 1,3-acetonedicarboxylate ,94%;Diethyl 1,3-acetonedicarboxylate ,96%;Diethyl 1,3-acetonedicarboxylate,Diethyl 3-oxoglutarate;Diethyl-3-oxo-pentan;Diethyl β-ketoglutarate;Diethyl 3-oxopentane-1,5-dioate, Diethyl acetone-1,3-dicarboxylate;Diethyl 1,3-acetonedicarboxylate, 95% 50ML;3-Oxopentanedioic acid, diethyl ester
34 prices
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Brand
  • AHH
  • AK Scientific
  • Alfa Aesar
  • Ambeed
  • American Custom Chemicals Corporation
  • Apolloscientific
  • Biosynth Carbosynth
  • Crysdot
  • Frontier Specialty Chemicals
  • Matrix Scientific
  • Sigma-Aldrich
  • SynQuest Laboratories
  • TCI Chemical
  • TRC
Package
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  • 25g
  • 25mL
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  • 50ML
  • 100g
  • 250g
  • 500g
  • 500mL
  • 1000g
  • 1kg
  • ManufacturerAHH
  • Product numberMT-09030
  • Product descriptionDiethyl 1,3-Acetonedicarboxylate 96%
  • Packaging1000g
  • Price$408
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ55922
  • Product descriptionDiethyl 1,3-Acetonedicarboxylate
  • Packaging25g
  • Price$20
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA10933
  • Product descriptionDiethyl acetone-1,3-dicarboxylate, 96%
  • Packaging50g
  • Price$44.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA10933
  • Product descriptionDiethyl acetone-1,3-dicarboxylate, 96%
  • Packaging250g
  • Price$157.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAmbeed
  • Product numberA103827
  • Product descriptionDiethyl 1,3-Acetonedicarboxylate 95%
  • Packaging5g
  • Price$6
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA103827
  • Product descriptionDiethyl 1,3-Acetonedicarboxylate 95%
  • Packaging25g
  • Price$10
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA103827
  • Product descriptionDiethyl 1,3-Acetonedicarboxylate 95%
  • Packaging100g
  • Price$33
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA103827
  • Product descriptionDiethyl 1,3-Acetonedicarboxylate 95%
  • Packaging500g
  • Price$111
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA103827
  • Product descriptionDiethyl 1,3-Acetonedicarboxylate 95%
  • Packaging1kg
  • Price$184
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberAPI0002331
  • Product descriptionDIETHYL 1,3-ACETONEDICARBOXYLATE 95.00%
  • Packaging50ML
  • Price$156.54
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberAPI0002331
  • Product descriptionDIETHYL 1,3-ACETONEDICARBOXYLATE 95.00%
  • Packaging1G
  • Price$619.7
  • Updated2021-12-16
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  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberAPI0002331
  • Product descriptionDIETHYL 1,3-ACETONEDICARBOXYLATE 95.00%
  • Packaging2.5G
  • Price$796.77
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberAPI0002331
  • Product descriptionDIETHYL 1,3-ACETONEDICARBOXYLATE 95.00%
  • Packaging5G
  • Price$912.29
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR11166
  • Product descriptionDiethyl 3-oxoglutarate
  • Packaging5g
  • Price$14
  • Updated2021-12-16
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  • ManufacturerApolloscientific
  • Product numberOR11166
  • Product descriptionDiethyl 3-oxoglutarate
  • Packaging25g
  • Price$65
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR11166
  • Product descriptionDiethyl 3-oxoglutarate
  • Packaging100g
  • Price$111
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AHH MT-09030 Diethyl 1,3-Acetonedicarboxylate 96% 1000g $408 2021-12-16 Buy
AK Scientific J55922 Diethyl 1,3-Acetonedicarboxylate 25g $20 2021-12-16 Buy
Alfa Aesar A10933 Diethyl acetone-1,3-dicarboxylate, 96% 50g $44.65 2024-03-01 Buy
Alfa Aesar A10933 Diethyl acetone-1,3-dicarboxylate, 96% 250g $157.65 2024-03-01 Buy
Ambeed A103827 Diethyl 1,3-Acetonedicarboxylate 95% 5g $6 2021-12-16 Buy
Ambeed A103827 Diethyl 1,3-Acetonedicarboxylate 95% 25g $10 2021-12-16 Buy
Ambeed A103827 Diethyl 1,3-Acetonedicarboxylate 95% 100g $33 2021-12-16 Buy
Ambeed A103827 Diethyl 1,3-Acetonedicarboxylate 95% 500g $111 2021-12-16 Buy
Ambeed A103827 Diethyl 1,3-Acetonedicarboxylate 95% 1kg $184 2021-12-16 Buy
American Custom Chemicals Corporation API0002331 DIETHYL 1,3-ACETONEDICARBOXYLATE 95.00% 50ML $156.54 2021-12-16 Buy
American Custom Chemicals Corporation API0002331 DIETHYL 1,3-ACETONEDICARBOXYLATE 95.00% 1G $619.7 2021-12-16 Buy
American Custom Chemicals Corporation API0002331 DIETHYL 1,3-ACETONEDICARBOXYLATE 95.00% 2.5G $796.77 2021-12-16 Buy
American Custom Chemicals Corporation API0002331 DIETHYL 1,3-ACETONEDICARBOXYLATE 95.00% 5G $912.29 2021-12-16 Buy
Apolloscientific OR11166 Diethyl 3-oxoglutarate 5g $14 2021-12-16 Buy
Apolloscientific OR11166 Diethyl 3-oxoglutarate 25g $65 2021-12-16 Buy
Apolloscientific OR11166 Diethyl 3-oxoglutarate 100g $111 2021-12-16 Buy

Properties

Melting point :125 °C
Boiling point :250 °C (lit.)
Density :1.113 g/mL at 25 °C (lit.)
refractive index :n20/D 1.440(lit.)
Flash point :187 °F
storage temp. :Sealed in dry,2-8°C
solubility :Chloroform (Slightly), Ethyl Acetate (Slightly)
pka :9.66±0.46(Predicted)
form :Liquid
color :Clear colorless to pale yellow
Water Solubility :10 g/L (20 ºC)
Sensitive :Moisture Sensitive
BRN :640146
InChIKey :ZSANYRMTSBBUCA-UHFFFAOYSA-N
CAS DataBase Reference :105-50-0(CAS DataBase Reference)
NIST Chemistry Reference :Pentanedioic acid, 3-oxo-, diethyl ester(105-50-0)
EPA Substance Registry System :Pentanedioic acid, 3-oxo-, diethyl ester (105-50-0)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H227 Combustible liquid Flammable liquids Category 4 Warning P210, P280, P370+P378, P403+P235,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to..…

Description

Synthesis of 1-substituted 4-ethoxycarbonyl-5- (ethoxycarbonylmethyl) pyrazoles Diethyl acetone-1, 3-dicarboxylate reacts with N, N-dimethylforma- mide dimethyl acetal (DMFDMA) in ethanol at room temperature. Unexpected product dichotomy is produced in the Biginelli-like condensation of 2-hydroxybenzaldehyde with urea or thiourea and dimethyl or diethyl acetone-1,3-dicarboxylate, respectively, as active methylene components. Ethyl 2-amino-4-(2-ethoxy-2-oxoethyl)thiazole-5-carboxylate (2a), prepared from diethylacetone-1,3-dicarboxylate, sulfuryl chloride and thiourea. Synthesis of diethyl 2,2-diethyl-3,5-dioxopimelate by the reaction of ethyl 3-chloro-3-oxo-2,2-dimethylpropionate with diethyl acetone-1,3-dicarboxylate.

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