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酸化亜鉛

酸化亜鉛 化學(xué)構(gòu)造式
1314-13-2
CAS番號(hào).
1314-13-2
化學(xué)名:
酸化亜鉛
別名:
亜鉛華;酸化亜鉛;亜鉛オキシド;酸化;酸化亜鉛, NANOTEKR;酸化亜鉛,3N5;透明性亜鉛白;酸化亜鉛(粉末);酸化亜鉛 PURISS. P.A.,ACS REAGENT,≥99.0% (KT);酸化亜鉛 PURISS.,MEETS ANALYTICAL SPECIFICATION OF PH. EUR.,BP,USP,99-100.5% (CALC. FOR DRIED SUBSTANCE);酸化亜鉛, -5ΜM, 99.9%;酸化亜鉛ナノ粒子(20NM);酸化亜鉛,0.02ΜM;酸化亜鉛, ACS;酸化亜鉛、分散液;酸化亜鉛 (99.999%-Zn) PURATREM;酸化亜鉛, 99.99% (metals basis);酸化亜鉛, sintered tablets (99.9%-Zn);酸化亜鉛, 99.7%;亜鉛華軟膏
英語(yǔ)名:
Zinc oxide
英語(yǔ)別名:
ZnO;Methicone;snowwhite;ZINC(II)OXIDE;Zinc oxide (ZnO);Zinc oxide, ACS, 99.0% min;zincite;ci77947;Zinkoxid;Zinc white
CBNumber:
CB3853034
化學(xué)式:
OZn
分子量:
81.39
MOL File:
1314-13-2.mol
MSDS File:
SDS

酸化亜鉛 物理性質(zhì)

融點(diǎn) :
1975 °C
沸點(diǎn) :
1949.9°C (estimate)
比重(密度) :
5.6
屈折率 :
2.008~2.029
閃點(diǎn) :
27℃
貯蔵溫度 :
Store at +5°C to +30°C.
溶解性:
0.0016g/l 不溶
外見(jiàn) :
ナノパウダー
比重:
5.61
色:
白色~淡黃色
PH:
7 (50g/l, H2O, 20℃)(slurry)
臭い (Odor):
灰色の粉または水晶、無(wú)臭、苦い好みへの白
水溶解度 :
1.6mg/L(29℃)
Crystal Structure:
ZnO型
晶系:
六方
Merck :
14,10147
空間群:
P63mc
晶格常數(shù):
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.324950.324950.5206990901200.0476
Dielectric constant:
40.0(20℃)
暴露限界値:
ACGIH: TWA 2 mg/m3; STEL 10 mg/m3
OSHA: TWA 5 mg/m3; TWA 15 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3; Ceiling 15 mg/m3
安定性::
安定。マグネシウム、強(qiáng)酸とは相容れない。
InChIKey:
XLOMVQKBTHCTTD-UHFFFAOYSA-N
CAS データベース:
1314-13-2(CAS DataBase Reference)
NISTの化學(xué)物質(zhì)情報(bào):
Zinc oxide(1314-13-2)
EPAの化學(xué)物質(zhì)情報(bào):
Zinc oxide (1314-13-2)
安全性情報(bào)
  • リスクと安全性に関する聲明
  • 危険有害性情報(bào)のコード(GHS)
主な危険性  N,Xn,F
Rフレーズ  50/53-20-43-36/38-20/21/22-67-66-10-11
Sフレーズ  60-61-7/9-36/37-26-16
RIDADR  UN 3077 9/PG 3
OEB B
OEL TWA: 5 mg/m3, Ceiling: 15 mg/m3
WGK Germany  2
RTECS 番號(hào) ZH4810000
TSCA  Yes
國(guó)連危険物分類(lèi)  9
容器等級(jí)  III
HSコード  28170000
有毒物質(zhì)データの 1314-13-2(Hazardous Substances Data)
毒性 LD50 orally in Rabbit: > 5000 mg/kg
IDLA 500 mg/m3
化審法 一般化學(xué)物質(zhì)
安衛(wèi)法 57,57-2
絵表示(GHS) GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
注意喚起語(yǔ) 危険
危険有害性情報(bào)
コード 危険有害性情報(bào) 危険有害性クラス 區(qū)分 注意喚起語(yǔ) シンボル P コード
H225 引火性の高い液體および蒸気 引火性液體 2 危険 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H319 強(qiáng)い眼刺激 眼に対する重篤な損傷性/眼刺激 性 2A 警告 GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H410 長(zhǎng)期的影響により水生生物に非常に強(qiáng)い毒性 水生環(huán)境有害性、慢性毒性 1 警告 GHS hazard pictograms P273, P391, P501
注意書(shū)き
P210 熱/火花/裸火/高溫のもののような著火源から遠(yuǎn)ざ けること。-禁煙。
P233 容器を密閉しておくこと。
P240 容器を接地すること/アースをとること。
P241 防爆型の電気機(jī)器/換気裝置/照明機(jī)器/...機(jī)器を使 用すること。
P273 環(huán)境への放出を避けること。
P305+P351+P338 眼に入った場(chǎng)合:水で數(shù)分間注意深く洗うこと。次にコ ンタクトレンズを著用していて容易に外せる場(chǎng)合は外す こと。その後も洗浄を続けること。

酸化亜鉛 価格 もっと(83)

メーカー 製品番號(hào) 製品説明 CAS番號(hào) 包裝 価格 更新時(shí)間 購(gòu)入
富士フイルム和光純薬株式會(huì)社(wako) W01W0126-0035 酸化亜鉛 99.0+% (ZnO) (mass/mass) (Titration)
Zinc Oxide 99.0+% (ZnO) (mass/mass) (Titration)
1314-13-2 500g ¥2800 2024-03-01 購(gòu)入
富士フイルム和光純薬株式會(huì)社(wako) W01ALF087812
Zinc oxide, 99.99% (metals basis)
1314-13-2 50g ¥21200 2024-03-01 購(gòu)入
関東化學(xué)株式會(huì)社(KANTO) 31579-2A 酸化亜鉛
Zinc oxide
1314-13-2 100g ¥44000 2024-07-01 購(gòu)入
関東化學(xué)株式會(huì)社(KANTO) 31579-1A 酸化亜鉛
Zinc oxide
1314-13-2 25g ¥14740 2024-07-01 購(gòu)入
Sigma-Aldrich Japan 96479 puriss. p.a., ACS reagent, ≥99.0% (KT)
Zinc oxide puriss. p.a., ACS reagent, ≥99.0% (KT)
1314-13-2 500g ¥10500 2024-03-01 購(gòu)入

酸化亜鉛 MSDS


C.I. pigment white 4

酸化亜鉛 化學(xué)特性,用途語(yǔ),生産方法

外観

白色の粉末

定義

本品は、直鎖狀のモノメチルポリシロキサンであり、次の化學(xué)式で表される。

溶解性

水, エタノールに不溶。酸, アルカリに可溶。水及びエタノール(99.5)にほとんど溶けない。希塩酸,希硫酸,希酢酸及び水酸化ナトリウム溶液に溶ける。

解説

酸化亜鉛,酸素と亜鉛の化合物。工業(yè)薬品、醫(yī)薬品、顔料などとしては亜鉛華、亜鉛白などということが多い。天然には紅亜鉛鉱として産する。

森北出版「化學(xué)辭典(第2版)

用途

塗料?印刷インキ?化粧品原料、醫(yī)薬、ゴム加硫促進(jìn)剤、陶磁器?ガラス原料、洗剤等、合成樹(shù)脂、繊維用添加剤、その他無(wú)機(jī)化學(xué)製品、色素(塗料、顔料)、紙用添加剤、その他添加剤、その他電子材料等製品、觸媒、メッキ剤

用途

ゴム用補(bǔ)強(qiáng)剤、顔料

用途

一般分析用、原料(醫(yī)薬、化粧品、蛍光體、ガスセンサー)。

用途

原料(醫(yī)薬、化粧品、塗料、顔料、觸媒等)、亜鉛塩製造原料、メッキ材料。

製法

シュウ酸亜鉛ZnC2O4を400℃で熱分解するか、塩基性炭酸亜鉛ZnCO3?3Zn(OH)2を熱分解させてつくる。工業(yè)的には金屬亜鉛を燃焼させてつくる。

化粧品の成分用途

閉塞剤、表面改質(zhì)剤、口腔ケア剤、皮膚保護(hù)剤、殺菌剤、増量剤、著色剤、紫外線(xiàn)吸収剤.散亂剤

効能

収斂薬, 皮膚保護(hù)薬

主な用途/役割

エポキシ樹(shù)脂系接著剤、ゴム系接著剤に使用される。

商品名

亜鉛華 (シオエ製薬); 亜鉛華 (マイラン製薬); 亜鉛華 (マイラン製薬); 亜鉛華 (吉田製薬); 亜鉛華 (小堺製薬); 亜鉛華 (日醫(yī)工); 亜鉛華 (日本ジェネリック); 亜鉛華 (日興製薬); 亜鉛華 (日興製薬); 亜鉛華 (東洋製薬化成); 亜鉛華 (東洋製薬化成); 亜鉛華 (東豊薬品); 亜鉛華軟膏 (小堺製薬); 酸化亜鉛 (三恵薬品); 酸化亜鉛 (丸石製薬); 酸化亜鉛 (健栄製薬); 酸化亜鉛 (司生堂製薬); 酸化亜鉛 (吉田製薬); 酸化亜鉛 (小堺製薬); 酸化亜鉛 (小堺製薬); 酸化亜鉛 (山善製薬); 酸化亜鉛 (日醫(yī)工); 酸化亜鉛 (日興製薬); 酸化亜鉛 (日興製薬)

使用上の注意

アルゴン封入

化學(xué)的特性

Zinc oxide is an amorphous, white or yellowish-white powder. It is a fine white powder that becomes yellow at temperatures above 3000℃. It is an amphoteric oxide that reacts with acids and dissolves in alkaline solution with formation of zincates. Its density and oil absorption value are 5.6 g/cm3 and 10-25 g oil/100 g ZnO, respectively.

物理的性質(zhì)

White or yellowish-white powder; odorless; bitter taste; hexagonal crystal; refractive index 2.008; density 5.606 g/cm3; melts at 1,975°C; practically insoluble in water, 1.6 mg/L at about 30°C; soluble in dilute acids, ammonia solu 990 tion, and alkali hydroxides.

使用

zinc oxide has been used to protect, soothe, and heal the skin. Zinc oxide provides an excellent barrier to the sun and other irritants. It is somewhat astringent, anti-septic, and anti-bacterial. When used in sunscreen preparations, it provides both uVA and uVB protection, and can contribute to and/or increase SPF. At the appropriate particle size, zinc oxide is transparent in the visible light spectrum but opaque in the uVC ranges, thereby avoiding a whitening effect when incorporated into sunscreen preparations. Zinc oxide is included on the FDA’s list of approved sunscreen chemicals. It demonstrates an impressive synergistic effect when combined with organic sunscreens. Zinc oxide is also used when a white color is desired for a product. It is obtained from zinc ore, a commonly found mineral, and is relatively non-allergenic.

製造方法

Zinc oxide is obtained as an intermediate in recovering zinc from minerals (See Zinc, Recovery). The oxide is prepared by vaporizing zinc metal and oxidation of the zinc vapors with preheated air (French process). The oxide can be produced by other processes. Another method involves roasting franklinite and other ores with coal and then oxidizing the product in air.

主な応用

ZnO is used primarily for its anti-bacterial and fungicidal properties. Also, in the United States, ZnO is regarded as a Category I skin protectant and a Category III sunscreen.

定義

zinc oxide: A powder, white whencold and yellow when hot, ZnO; r.d.5.606; m.p. 1975°C. It occurs naturallyas a reddish orange ore zincite,and can also be made by oxidizinghot zinc in air. It is amphoteric,forming zincates with bases. It isused as a pigment (Chinese white) and a mild antiseptic in zinc ointments.An archaic name is philosopher’swool.

一般的な説明

Crude zinc oxide is a yellow-gray granular solid with no odor. Zinc oxide has a specific gravity of 4.4. Zinc oxide is insoluble in water. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. Prolonged inhalation of the dust may result in metal fume fever with symptoms of chills, fever, muscular pain, nausea and vomiting.

空気と水の反応

Slowly decomposed(hydrolyzed) in water. Insoluble in water.

反応プロフィール

ZINC OXIDE is insoluble in water. What little solubility Zinc oxide has yields aqueous solutions that are neutral in pH. Intimate mixtures of zinc oxide and chlorinated rubber with or without hydrocarbons or chlorinated solvent react violently, even explosively upon heating [Chem. Trade J., 1962, 151, 672]. Slow addition of zinc oxide to cover the surface of linseed oil varnish caused generation of heat and ignition, [Chem. Trade J., 1933, 92, 278].

危険性

Exposure to zinc oxide fumes from welding and other operations can cause metal fume fever. Its symptoms are chills, fever, cough, and tightness in the chest.

健康ハザード

Exposures to zinc oxide metal fume cause several health disorders. The symptoms of toxicity include, but are not limited to, fever, chills, muscle ache, nausea, fever, dry throat, cough; lassitude (weakness, exhaustion), metallic taste, headache, blurred vision, low back pain, vomiting, malaise (vague feeling of discomfort), chest tightness, dyspnea (breathing diffi culty) and decreased pulmonary function. The overexposure to zinc oxide fumes in workplaces produce symptoms known as metal fume fever or “zinc shakes”; an acute, selflimiting condition. Chronic exposure to zinc oxide may cause respiratory tract irritation with nasopharyngitis and laryngitis.

火災(zāi)危険

Some may burn but none ignite readily. Containers may explode when heated. Some may be transported hot.

化學(xué)性質(zhì)

隠ぺい力はそれほど大きくないが,著色力は酸化チタンには及ばないものの鉛白よりは大きい

農(nóng)業(yè)用途

Zinc oxide (ZnO) is a zinc fertilizer. It is a white powder when cold and yellow when hot, and contains approximately 78% zinc.
Zinc oxide occurs in nature as a reddish-orange colored zincite, and is made by oxidizing hot zinc in air. It is an amphoteric oxide forming zincates, by reacting with bases and zinc salts with acids. It is used as a white pigment and as a mild antiseptic in ointments. An archaic name of zinc oxide is philosopher's wool.
Foliar applications with zinc oxide reduce the foliage damage. Zinc oxide, applied by way of seed coatings, root dips or tree injections, corrects the zinc deficiency. Dipping potato seeds in 2% zinc oxide suspension overcomes zinc deficiency satisfactorily. A similar method is used for pre-plant dipping of the roots of rice seedlings.

応用例(製薬)

The pharmaceutical and cosmetic industries use ZnO in powders and ointments because of its bactericidal properties. It is also used to form dental cements by its reaction with eugenol.
Zinc oxide is used as a raw material for many products: stearates, phosphates, chromates, bromates, organic dithiophosphates, and ferrites (ZnO, MnO, Fe2O3). It is used as a source of zinc in animal feeds and in electrogalvanization . It is also used for desulfurizing gases.

工業(yè)用途

Zinc oxide has many uses. By far the most important is in the rubber industry. Almost half the world’s ZnO is used as an activator for vulcanization accelerators in natural and synthetic rubber. The reactivity of the ZnO is a function of its specific surface area, but is also influenced by the presence of impurities such as lead and sulfates. The ZnO also ensures good durability of the vulcanized rubber, and increases its thermal conductivity. The ZnO content is usually 2–5%.
In paints and coatings, zinc oxide is no longer the principal white pigment, although its superb white color is used by artists. It is used as an additive in exterior paints for wood preservation. It is also utilized in antifouling and anticorrosion paints [2.82]. It improves film formation, durability, and resistance to mildew (having a synergistic effect with other fungicides) because it reacts with acidic products of oxidation and can absorb UV radiation.
In the field of glass, ceramics, and enamels, ZnO is used for its ability to reduce thermal expansion, to lower the melting point, and to increase chemical resistance. It can also be used to modify gloss or to improve opacity.

材料の用途

The highest purity material is calcined with additives such as Bi2O3 and used in the manufacture of varistors. The photoconducting properties of ZnO are used in photoreproduction processes. Doping with alumina causes a reduction in electrical resistance; hence, it can be used in the coatings on the master papers for offset reproduction.
Zinc oxide is used as a catalyst in organic syntheses (e.g., of methanol), often in conjunction with other oxides. It is present in some adhesive compositions.

安全性プロファイル

Moderately toxic to humans by ingestion. Poison experimentally by intraperitoneal route. An experimental teratogen. Other experimental reproductive effects. Human systemic effects by inhalation of freshly formed fumes: metal fume fever with chills, fever, tightness of chest, cough, dyspnea, and other pulmonary changes. Mutation data reported. A s h and eye irritant. Has exploded when mixed with chlorinated rubber. Violent reaction with Mg, linseed oil. When heated to decomposition it emits toxic fumes of ZnO. See also ZINC COMPOUNDS.

職業(yè)ばく露

Zinc oxide is primarily used as a white pigment in rubber formulations and as a vulcanizing aid. It is also used as an antiinflammatory agent; in photo copying; paints, chemicals, ceramics, lacquers, and varnishes; as a filler for plastic; in cosmetics; pharmaceuticals, and calamine lotion. Exposure may occur in the manufacture and use of zinc oxide and products, or through its formation as a fume when zinc or its alloys are heated. HC may have been used as a Choking/Pulmonary Agent.

発がん性

In general, genotoxic studies have not found evidence for mutagenicity of zinc.

輸送方法

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

合成方法

通過(guò)鋅的氧化反應(yīng)制得

不和合性

Incompatible with linseed oil, magnesium. Contact with chlorinated rubber (@ 215C) may cause a violent reaction. Slowly decomposed by water.

參考文獻(xiàn)

R.B. Heller, J. McGannon, A.H. Weber, J. Appl. Phys., 21, 1283 (1950), DOI: 10.1063/1.1699591.

酸化亜鉛 上流と下流の製品情報(bào)

原材料

準(zhǔn)備製品


酸化亜鉛 生産企業(yè)

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酸化亜鉛  スペクトルデータ(IR1、Raman)


1314-13-2(酸化亜鉛)キーワード:


  • 1314-13-2
  • Zinc oxide, Puratronic(R), 99.9995% (metals basis)
  • Zinc oxide, 99.9% (metals basis)
  • Zinc oxide, Puratronic(R), 99.999% (metals basis)
  • ZINC OXIDE POWDER
  • Zinc Oxide (fume) (also see metal)
  • Zinc Oxide Dust
  • ZINC OXIDE extrapure AR
  • NIST SRM 674 (Renewals) Zinc oxide
  • ZnO 99.9%: 51mm dia. x 6mm: hot pressed:
  • ZnO/Ga2O3 5% wt%: 99.9%: 51mm x 6mm: hot pressed:
  • Zinc oxide, NanoGard|r
  • Zinc oxide, NanoShield ZN-3010, 50% in H2O, colloidal dispersion with nonionic dispersant
  • Zinc oxide, Nanotek
  • Zinc oxide, 99% min
  • Zinc oxide, NanoShield ZN-2000, 50% in H2O, colloidal dispersion with nonionic dispersant
  • Zinc oxide, Puratronic, 99.999% (metals basis)
  • Zinc oxide, Puratronic, 99.9995% (metals basis)
  • ZnO/Al 2% wt%: 99.9%: 51mm dia x 6mm: hot pressed:
  • Zinc oxide, NanoTek Z1102PMA, 50% in 1,2-Propanediol monomethyl ether acetate, colloidal dispersion
  • Zinc oxide, NanoTek|r C1, 99%, organo-silane coated, hydrophopic, nonpolar
  • Zinc oxide, NanoTek|r C2, 99%, organo-silane coated, hydrophopic, nonpolar
  • Zinc oxide, Pharma Eur.
  • zinc oxide, puratronic
  • ZINCOXIDE,POWDER,REAGENT,ACS
  • ZINCOXIDE,TECHNICAL
  • ZINCFUMES
  • actox16
  • actox216
  • ai3-00277
  • akro-zincbar85
  • 亜鉛華
  • 酸化亜鉛
  • 亜鉛オキシド
  • 酸化
  • 酸化亜鉛, NANOTEKR
  • 酸化亜鉛,3N5
  • 透明性亜鉛白
  • 酸化亜鉛(粉末)
  • 酸化亜鉛 PURISS. P.A.,ACS REAGENT,≥99.0% (KT)
  • 酸化亜鉛 PURISS.,MEETS ANALYTICAL SPECIFICATION OF PH. EUR.,BP,USP,99-100.5% (CALC. FOR DRIED SUBSTANCE)
  • 酸化亜鉛, -5ΜM, 99.9%
  • 酸化亜鉛ナノ粒子(20NM)
  • 酸化亜鉛,0.02ΜM
  • 酸化亜鉛, ACS
  • 酸化亜鉛、分散液
  • 酸化亜鉛 (99.999%-Zn) PURATREM
  • 酸化亜鉛, 99.99% (metals basis)
  • 酸化亜鉛, sintered tablets (99.9%-Zn)
  • 酸化亜鉛, 99.7%
  • 亜鉛華軟膏
  • 酸化亜鉛 (JP17)
  • 亜鉛華軟膏 (JP17)
  • 酸化亜鉛(II)?
  • メチコン
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