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ChemicalBook >> CAS DataBase List >>2,6-Dimethyl-4-heptanone

2,6-Dimethyl-4-heptanone

CAS No.
108-83-8
Chemical Name:
2,6-Dimethyl-4-heptanone
Synonyms
DIBK;DIISOBUTYL KETONE;ISOBUTYL KETONE;2,6-Dimethylheptan-4-one;VALERONE;FEMA 3537;NSC 15136;isovaleron;NSC 406913;ISOVALERONE
CBNumber:
CB8852764
Molecular Formula:
C9H18O
Molecular Weight:
142.24
MDL Number:
MFCD00008940
MOL File:
108-83-8.mol
Last updated:2024-12-18 14:15:32

2,6-Dimethyl-4-heptanone Properties

Melting point -46 °C
Boiling point 165-170 °C(lit.)
Density 0.808 g/mL at 25 °C(lit.)
vapor density 4.9 (vs air)
vapor pressure 1.7 mm Hg ( 20 °C)
FEMA 3537 | 2,6-DIMETHYL-4-HEPTANONE
refractive index n20/D 1.412(lit.)
Flash point 120 °F
storage temp. Store below +30°C.
solubility Miscible with ethanol, ether, carbon tetrachloride, chloroform, benzene and most organic liquids.
form Liquid
Specific Gravity 0.810 (20/4℃)
color Clear colorless to slightly yellow
Odor Sweet Pineapple-Banana-like fruity taste, but with a somewhat harsh chemical note.
Odor Type green
explosive limit 0.8-6.2%, 100°F
Water Solubility 0.05 g/100 mL
JECFA Number 302
BRN 1743163
Henry's Law Constant 6.36(x 10-4 atm?m3/mol) at 20 °C (approximate - calculated from water solubility and vapor pressure)
Exposure limits TLV-TWA 150 mg/m3 (25 ppm); IDLH 1000 ppm.
Dielectric constant 9.9100000000000001
Stability Stable. Flammable. Incompatible with strong oxidizing agents.
LogP 3.71 at 20℃
Substances Added to Food (formerly EAFUS) DIISOBUTYL KETONE
FDA 21 CFR 175.105
CAS DataBase Reference 108-83-8(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII V52W30H1BU
NIST Chemistry Reference 4-Heptanone, 2,6-dimethyl-(108-83-8)
EPA Substance Registry System Diisobutyl ketone (108-83-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H335
Precautionary statements  P210-P233-P240-P241-P242-P243
Hazard Codes  Xi
Risk Statements  10-37
Safety Statements  24
OEB A
OEL TWA: 25 ppm (150 mg/m3)
RIDADR  UN 1157 3/PG 3
WGK Germany  1
RTECS  MJ5775000
Autoignition Temperature 745 °F
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29141990
Hazardous Substances Data 108-83-8(Hazardous Substances Data)
Toxicity LD50 orally in Rabbit: 5750 mg/kg LD50 dermal Rabbit 16000 mg/kg
IDLA 500 ppm
NFPA 704
2
1 0

2,6-Dimethyl-4-heptanone price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.18831 Diisobutyl ketone for synthesis 108-83-8 1L $65.3 2024-03-01 Buy
Sigma-Aldrich 273848 2,6-Dimethyl-4-heptanone 99% 108-83-8 25g $123 2024-03-01 Buy
Sigma-Aldrich 273848 2,6-Dimethyl-4-heptanone 99% 108-83-8 100g $399 2024-03-01 Buy
Sigma-Aldrich 8.18831 Diisobutyl ketone for synthesis 108-83-8 100mL $23 2023-06-20 Buy
TCI Chemical D0733 2,6-Dimethyl-4-heptanone >90.0%(GC) 108-83-8 25mL $16 2024-03-01 Buy
Product number Packaging Price Buy
8.18831 1L $65.3 Buy
273848 25g $123 Buy
273848 100g $399 Buy
8.18831 100mL $23 Buy
D0733 25mL $16 Buy

2,6-Dimethyl-4-heptanone Chemical Properties,Uses,Production

Description

2, 6-Dimethyl-4-heptanone, also known as diisobutyl ketone, belongs to the family of ketones, being a flavoring ingredient. It can also be used as the extraction solvent for the determination of ten trace metals (V, Cr, Fe, Co, Ni, Cu, Zn, Mo, Cd, Pb) in aqueous samples with plasma atomic emission spectrometry. Similar logic can also be applied to the measurement of phosphorus using 2, 6-dimethyl-4-heptanone as the extraction agent. It is also an important organic solvent widely used as industrial intermediates.

Chemical Properties

5-Methyl-3-heptanone is a colorless liquid with low solubility in water (0.3 wt %); water is poorly soluble in the ketone (0.9 wt %). 5-Methyl-3-heptanone is highly soluble in common organic solvents.

Physical properties

Clear, colorless liquid with a mild, sweet, ether-like odor. Odor threshold concentration is 0.11 ppm (quoted, Amoore and Hautala, 1983).

Occurrence

Reported found in baked potato and wheaten bread.

Uses

Diisobutyl ketone is used as a solvent fornitrocellulose, lacquers, and synthetic resins;in organic syntheses.

Uses

2,6-Dimethyl-4-heptanone is used as a coating solvent. It is an active component of mint oil. It acts as a dispersant for organosol type resins. It is involved in the antigerminative treatment of bulbs and tubers. Further, it is used as a solvent for nitrocellulose. In addition to this, it acts as an intermediate in the preparation of inhibitors, active pharmaceutical ingredients and dyes.

Uses

Diisobutyl ketone (DIBK) is a transparent liquid with a distinct odor and a high boiling point. It is an heavy-end byproduct of producing MIBK. DIBK is used in many applications such as nitrocellulose lacquers, synthetic resins, coatings and stains, paint strippers, leather finishings, adhesives, printing and coating inks, cleaning and dregreasing, Flavors and fragrances, solvent and re-crystallization aid for pharmaceuticals, mining, and as a chemical intermediate. DIBK has good activity for many synthetic resins including nitrocellulose, rosin esters, phenolics, hydrocarbons, alkyds, polyesters, and acrylics. It is useful as a retarder solvent to improve flow and minimize humidity blushing. The low density and low surface tension of DIBK enables formulators to develop high-solids coatings with low VOC content and excellent flow and leveling properties. DIBK has excellent viscosity reduction for and reduces surface tension in high solid’s coatings. It has good volume-to-weight advantage over other classes of solvents used in coatings. It is a non-HAP (Hazardous Air Pollutant) solvent.

Uses

Diisobutyl Ketone is a component of mint oil and L-carvone solutions for fungicidal and antigerminative treatment of bulbs and tubers.

Definition

ChEBI: 2-Methyl-4-heptanone is a ketone.

Production Methods

Diisobutyl ketone is produced by hydrogenation of phorone or by metal-catalyzed decomposition of isovaleric acid.It is also a by-product in the manufacture of methyl isobutyl ketone.

Synthesis Reference(s)

Journal of the American Chemical Society, 95, p. 6876, 1973 DOI: 10.1021/ja00801a081

General Description

A clear colorless liquid. Flash point 140°F. Less dense than water and insoluble in water. Vapors heavier than air.

Air & Water Reactions

Flammable. Insoluble in water.

Reactivity Profile

2,6-Dimethyl-4-heptanone may attack some plastics. 2,6-Dimethyl-4-heptanone reacts with oxidizers.

Health Hazard

Inhalation of vapor causes irritation of nose and throat. Ingestion causes irritation of mouth and stomach. Vaporirritates eyes. Contact with liquid irritates skin.

Health Hazard

Inhalation of the vapors of diisobutyl ketonecan produce irritation of the eyes, nose, andthroat. At 25 ppm its odor was unpleasant, but the irritation effect on humanswas insignificant. At 50 ppm the irritationwas mild. A 7- hour exposure to 125 ppmhad no adverse effect on rats; however, at250 ppm, female rats developed increasedliver and kidney weights. An 8-hour exposure to 2000 ppm was lethal. Ingestion ofthis compound can cause the symptoms ofheadache, dizziness, and dermatitis.
LD50 value, oral (rats): 5.8 g/kg.

Flammability and Explosibility

Not classified

Chemical Reactivity

Reactivity with Water No reaction; Reactivity with Common Materials: May attack some forms of plastics; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

Moderately toxic by ingestion and inhalation. Mddly toxic by skin contact. Human systemic effects by inhalation: headache, nausea or vomiting, and unspecified eye effects. An eye and skin irritant. Narcotic in high concentrations. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use Con, dry chemical, water spray, mist or fog. When heated to decomposition it emits acrid smoke and fumes. See also KETONES.

Potential Exposure

Human Data;Primary Irritant. Diisobutyl ketone is used as a solvent; as a dispersant for resins; and as an intermediate in the synthesisof pharmaceuticals and pesticides.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the

Environmental Fate

Biological. Using the BOD technique to measure biodegradation, the mean 5-d BOD value (mM BOD/mM diisobutyl ketone) and ThOD were 4.86 and 37.4%, respectively (Vaishnav et al., 1987).
Chemical/Physical. Diisobutyl ketone will not hydrolyze because it has no hydrolyzable functional group.
At an influent concentration of 300 mg/L, treatment with GAC resulted in nondetectable concentrations in the effluent. The adsorbability of the carbon used was 60 mg/g carbon (Guisti et al., 1974).

storage

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials. Prior to working with DIBK you should be trained on itsproper handling and storage. Before entering confined spacewhere DIBK may be present, check to make sure that anexplosive concentration does not exist. Store in tightlyclosed containers in a cool, well-ventilated area. Metal containers involving the transfer of this chemical should begrounded and bonded. Where possible, automatically pumpliquid from drums or other storage containers to processcontainers. Drums must be equipped with self-closingvalves, pressure vacuum bungs, and flame arresters. Useonly nonsparking tools and equipment, especially whenopening and closing containers of this chemical. Sources ofignition, such as smoking and open flames, are prohibitedwhere this chemical is used, handled, or stored in a mannerthat could create a potential fire or explosion hazard.Wherever this chemical is used, handled, manufactured, orstored, use explosion-proof electrical equipment andfittings.

Shipping

This compound requires a shipping label of“FLAMMABLE LIQUID.” It falls in Hazard Class 3 andPacking Group II.

Incompatibilities

Forms explosive mixture with air.Incompatible with strong acids, aliphatic amines, strongoxidizers. Attacks some forms of plastics, coatings, andrubber.

Waste Disposal

Incineration, molten metal salt destruction.

References

Bone, K. M., and W. D. Hibbert. "Solvent extraction with ammonium pyrrolidinedithiocarbamate and 2,6-dimethyl-4-heptanone for the determination of trace metals in effluents and natural waters." Analytica Chimica Acta 107.JUN(1979):219-229.
Miyazaki, Akira, A. Kimura, and Y. Umezaki. "Determination of ng ml-1 levels of phosphorus in waters by diisobutyl ketone extraction and inductively coupled plasma atomic emission spectrometry." Analytica Chimica Acta 127.96(1981):93-101.
Zhang, Fagen, et al. "Comparative metabolism and pharmacokinetics of diisobutyl ketone and diisobutyl carbinol in male SD rats." Toxicology Letters 232.1(2015):175-181.

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View Lastest Price from 2,6-Dimethyl-4-heptanone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Diisobutyl ketone / 2,6-DIMETHYL-4-HEPTA pictures 2024-10-28 Diisobutyl ketone / 2,6-DIMETHYL-4-HEPTA
108-83-8
 US $1.00 / KG 1KG 99% 10 mt Hebei Weibang Biotechnology Co., Ltd
2,6-Dimethyl-4-heptanone pictures 2024-10-11 2,6-Dimethyl-4-heptanone
108-83-8
 US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Chuanghai Biotechnology Co,.LTD
2,6-Dimethyl-4-heptanone pictures 2023-08-10 2,6-Dimethyl-4-heptanone
108-83-8
 US $10.00 / kg 1kg 99% 500t/month Henan Bao Enluo International TradeCo.，LTD
2,6-DIMETHYL-4-HEPTANONE 2,6-Dimethyl-4-heptanone, remainder mainly 4,6-dimethyl-2-heptanone Diisobutyl ketone~Isovalerone Dimethylheptanone 2 6-DIMETHYL-4-HEPTANONE 99+% 2,6-DIMETHYL-4-HEPTANONE, TECH., 80% 2,6-Dimethyl-4-Heptanone,Purified 2,6-Dimethyl-4-heptanone, remainder mainly 4,6-dimethyl-2-heptanone, tech., 80% isovaleron VALERONE S-DIISOPROPYLACETONE 2,6-dimetil-eptan-4-one (italian) 2,6-DIMETHYL-4-HEPTANONE,98+% 2,6-DIMETHYL-4-HEPTANONE, MIXTURE OF ISOMERS, 98%, CA 2:1 WI 2,6-Dimethyl-4-heptanone, mixture of isomers, 98%, ca 2:1 with 4,6-dimethyl-2-heptanone 2,6-DIMETHYL-4-HEPTANONE, PURE 2,6-dimethylheptan-4-one di-isobutyl ketone Di Isobutyl Ketone (DIBK) DIBK, Diisobutyl ketone, Isovalerone ISOVALERONE FEMA 3537 (iso-C4H9)2CO 2,5-Dimethyl-4-heptanone 2,6-dimethyl-4-heptanon 2,6-dimethyl-4-heptanone (diisobutyl ketone) 2,6-Dimethyl-heptan-4-on 2,6-Dimethylheptan-4-on 2,6-dimethyl-heptan-4-on(dutch,german) 2,6-dimethyl-heptan-4-one 2,6-Dimetil-eptan-4-one 4-Heptanone,2,6-dimethyl- dibutylketone(non-specificname) Diisobutilchetone DiMethyl-4-heptan 2,6-Dimethyi-4-heptanone Diisobutyl ketone for synthesis 2,6-Dimethyl-4-heptanone, (sum of 2,6-Dimethyl-4-heptanone & 4,6-Dimethyl-2-heptanone) diisobutylcetone Di-isobutylcetone di-isobutylcetone(french) Diisobutylketon diisobutylketon(dutch,german) Diisopropylacetone sec-diisopropylacetone sym-Diisopropylacetone 2,6-Dimethyl-4-heptanone technical grade 2,6-Dimethyl-4-heptanone, 80%, remainder mainly 4,6-dimethyl-2-heptanone, tech. Diisobutyl ketone, extra pure 2,6-Dimethyl-4-heptanone,Diisobutyl ketone, Isovalerone 2,6-2-4-heptanone 2,6-DiMethyl-4-heptanone, >90% (suM of 2,6-DiMethyl-4-heptanone & 4,6-DiMethyl-4-heptanone) 2,6-DiMethyl-4-heptanone, >90% (suM of 2,6-DiMethyl-4-heptanone & 4,6-DiMethyl-2-heptanone) 2,6-Dimethyl-4-heptanone, mixture of isomers, 97%, ca 2:1 with 4,6-dimethyl-2-heptanone NSC 15136 NSC 406913 2,6-Dimethyl-4-Heptanone (Dibk ) 2,6-Dimethyl-4-heptanone(DIBK)Solution,2000mg/L,1ml 2,6-Dimethyl-4-heptanone(DIBK)Solution,1000mg/L,1ml