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ChemicalBook >> CAS DataBase List >>9,10-Diphenylanthracene

9,10-Diphenylanthracene

CAS No.
1499-10-1
Chemical Name:
9,10-Diphenylanthracene
Synonyms
9,10-DiphenyL;9,10-biphenylanthracene;DPHA、DPA;9,10-DPA;9,10-Diphenyla;9,10-Diphenylanthrac;9,1-Diphenylanthracene;9, 9-diphenylanthracene;9,10-diphenyl-anthracen;9,10-DIPHENYLANTHRACENE
CBNumber:
CB5132335
Molecular Formula:
C26H18
Molecular Weight:
330.42
MDL Number:
MFCD00001253
MOL File:
1499-10-1.mol
MSDS File:
SDS
Last updated:2024-12-18 14:08:52

9,10-Diphenylanthracene Properties

Melting point 245-248 °C(lit.)
Boiling point 485°C(lit.)
Density 1.1398 (estimate)
refractive index 1.8430 (estimate)
storage temp. Store below +30°C.
form Fine Crystalline Powder
color Light yellow to beige
Water Solubility INSOLUBLE
λmax 393nm(Cyclohexane)(lit.)
BRN 1914010
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey FCNCGHJSNVOIKE-UHFFFAOYSA-N
CAS DataBase Reference 1499-10-1(CAS DataBase Reference)
FDA UNII 51BQ8IYQ9U
NIST Chemistry Reference Anthracene, 9,10-diphenyl-(1499-10-1)
EPA Substance Registry System Anthracene, 9,10-diphenyl- (1499-10-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P280-P302+P352-P362+P364
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-36/37-26
RIDADR  2811
WGK Germany  3
RTECS  SS6825000
TSCA  Yes
HS Code  29029080
NFPA 704
1
1 0

9,10-Diphenylanthracene price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich D205001 9,10-Diphenylanthracene 97% 1499-10-1 1g $74.8 2024-03-01 Buy
Sigma-Aldrich D205001 9,10-Diphenylanthracene 97% 1499-10-1 5G $341 2024-03-01 Buy
Sigma-Aldrich 8.20529 9,10-Diphenylanthracene for synthesis 1499-10-1 1g $64.9 2024-03-01 Buy
Sigma-Aldrich 8.20529 9,10-Diphenylanthracene for synthesis 1499-10-1 5G $233 2024-03-01 Buy
Sigma-Aldrich 45788 9,10-Diphenylanthracene analytical standard 1499-10-1 250mg $72.5 2024-03-01 Buy
Product number Packaging Price Buy
D205001 1g $74.8 Buy
D205001 5G $341 Buy
8.20529 1g $64.9 Buy
8.20529 5G $233 Buy
45788 250mg $72.5 Buy

9,10-Diphenylanthracene Chemical Properties,Uses,Production

Chemical Properties

9,10-Diphenylanthracene is a fluorescent compound, slightly yellow powder with an excitation peak at 314 nm and an emission peak at 302 nm. It is spectrally similar to MCA (7-Methoxycoumarin-4-acetic acid). 

Uses

9,10-Diphenylanthracene acts as a sensitizer in chemiluminescence. It is used in light sticks in order to produce blue light. It is also useful in blue organic light-emitting diodes (OLEDs) and OLED-based displays. Further, it plays an important role in the preparation of 9,10-difluoro-9,10-diphenyl-9,10-dihydro-anthracene. In addition to this, it is used as an organic semiconductor.

Definition

ChEBI: 9,10-diphenylanthracene is a member of the class of anthracenes that is anthracene in which both of the hydrogens on the central ring are substituted by phenyl groups. It has a role as a fluorochrome and a photosensitizing agent.

Application

9,10-Diphenylanthracene is a polycyclic aromatic hydrocarbon and a useful organic semiconductor. 9,10-Diphenylanthracene is also a sensitiser in chemiluminescence. It has applications related to OLEDs and OLED-based displays.

General Description

9,10-Diphenylanthracene, an aromatic hydrocarbon, is a blue light emitting material that is used for the measurement of fluorescence quantum yields in dilute solutions. Its derivatives show potential candidature in organic light emitting diode (OLED) devices. It is also used as a fluorophore for the study of peroxyoxalate chemiluminescence (POCL).

Synthesis

9, 10 – Diphenylanthracene was synthesized via a multistep synthesis using 9, 10 – dibromoanthracene, a Suzuki coupling was performed using phenylboronic acid over a tetrakis(triphenylphosphine)palladium(0) catalyst to form the title compound:
The mixture of 1,3-dibromobenzene (236 mg, 1.0 mmol), phenylboronic acid (271 mg, 2.2 mmol), and Na2CO3 (424 mg, 4 mmol) was taken up in DMF (2 mL) and then ARF-Pd (300 mg, 0.01 mmol Pd) was added. The mixture was heated under N2 at 110 °C for 2.5 h. After cooling, the mixture was diluted with cold H2O (10 mL) and filtered through a cotton bed. The filtrate was extracted with Et2O (3 × 20 mL) and the combined organic extracts were washed with brine (10 mL), dried (Na2SO4), and evaporated. The residue was purified by column chromatography (silica gel, PE) to give 9,10-Diphenylanthracene (4d), yield 90%. Mp 245-247 °C (Lit.36 245-48 °C). IR (Nujol): 1458, 1377 cm-1. 1H NMR (300 MHz, CDCl3): δ = 7.72-7.66 (m, 4 H), 7.62-7.46 (m, 10 H), 7.34-7.29 (m, 4 H). 13C NMR (75 MHz, CDCl3): δ = 139.1, 137.1, 131.3, 129.8, 128.4, 127.4, 126.9, 125.0.
9,10-Diphenylanthracene synthesis

Purification Methods

Crystallise the anthracene from acetic acid or xylene [Baumstark et al. J Org Chem 52 3308 1987]. [Beilstein 5 IV 2807.]

19061-38-2
1499-10-1
Synthesis of 9,10-Diphenylanthracene from 9,10-Epoxyanthracene, 9,10-dihydro-9,10-diphenyl-

9,10-Diphenylanthracene Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 352)Suppliers
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Yurui (Shanghai) Chemical Co., Ltd.
+86-021-50456736 +8613761615711 yuki@riyngroup.com China 1028 58
Hu Bei Jiutian Bio-medical Technology CO.,Ltd
027-88013699 17354350817 Ryan@jiutian-bio.com China 6001 58
Hebei Xinsheng New Material Technology Co., LTD. 		+86-16632316109 xinshengkeji@xsmaterial.com China 1085 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29791 60
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Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32957 60
AB PharmaTech,LLC 		323-480-4688 sales@acrospharmatech.com United States 989 55
Beijing Green Guardee Technology Co., Ltd 		86-010-69706062 sales2@greenguardee.com CHINA 650 58
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29880 58

View Lastest Price from 9,10-Diphenylanthracene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
9,10-Diphenylanthracene pictures 2024-12-13 9,10-Diphenylanthracene
1499-10-1
 US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
Purple fluorescence dye DPHA pictures 2024-12-10 Purple fluorescence dye DPHA
1499-10-1
 US $0.00 / KG 1KG 98.00% 150KG /month Shanghai Daken Advanced Materials Co.,Ltd
9,10-Diphenylanthracene pictures 2023-11-08 9,10-Diphenylanthracene
1499-10-1
 US $0.00-0.00 / kg 1kg 99.9% 30000 KG Hebei Xinsheng New Material Technology Co., LTD.
9,10-Diphenylanthracene (purified by subliMation) 9,10-Diphenyla 9, 9-diphenylanthracene Purple fluorescence dye DPHA 9,10-diphenyl-anthracen 9,10-Diphenylanthracene, 98% 1GR 9,10-Diphenylanthracene, 98% 5GR anthracene,9,10-diphenyl- 9,10-DIPHENYLANTHRACENE 9,10-DIPHENYLANTHRACEN 97% 9,10-DIPHENYLENEANTHRACENE OEKANAL, 250 Bis(2,4,6-Trichlorophenyl)EthanedioateTcpo 9,10-Diphenylanthracene, scintillation grade, 99+% 9,10-Diphenylanthracene,98% 9,10-Diphenylanthracene(blue) (DPA) 9.10-Diphenyl anthracene 100mg [1499-10-1] 9,10-DiphenylanthraceneDISC 05/09/02 9,10-Diphenylanthrac DPHA、DPA 9,10-Dipehnylphenanthrene 9,10-Diphenylanthracene@50 μg/mL in Toluene 9,10-Diphenylanthracene > 9,10-Diphenylanthracene(purifiedbysublimation)> 9,10-DiphenylanthraceneSolution,500mg/L,1ml 9,10-DIPHENYLANTHRACENE FOR SYNTHESIS 9,10-diphenylanthracene (DPHA ) 9,1-Diphenylanthracene 9,10-biphenylanthracene 9,10-DiphenyL 9,10-Diphenylanthracene (DPA) 9,10-DPA 9,10-Diphenylanthracene in Cyclohexane 9,10-Diphenylanthracene in Acetonitrile Trofinetide Impurity 22 1499-10-1 C26H8 C26H18 C14H8C6H52 Arenes Building Blocks Electroluminescence Anthracenes Organic Building Blocks Photoluminescent Materials > Light-Emitting Dopants and Fluorescent Dyes Photonic and Optical Materials DIO - DIZChemical Class Alpha Sort Analytical Standards AromaticsVolatiles/ Semivolatiles Chemical Class D DAlphabetic Hydrocarbons NeatsAnalytical Standards PAHs Industrial/Fine Chemicals Scintillators Anthracenes