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ChemicalBook >> CAS DataBase List >>1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis(di-tert-butylphosphino)ferrocene

CAS No.
84680-95-5
Chemical Name:
1,1'-Bis(di-tert-butylphosphino)ferrocene
Synonyms
DTBPF;1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE;DBtPF;98% DtBPF;1,1'-Bis(di-t-butyL;1,1'-Bis(di-tert-butylphosphi;1,1'-Bis(di-tert-butylphosphin;1,1'-Bis(di-t-butylphosphino)ferrocene;1,1'-Bis(di-tert-butylphosphiNA)ferrocene;1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
CBNumber:
CB3689138
Molecular Formula:
C26H44FeP210*
Molecular Weight:
474.42
MDL Number:
MFCD01630818
MOL File:
84680-95-5.mol
MSDS File:
SDS
Last updated:2024-11-11 14:08:43

1,1'-Bis(di-tert-butylphosphino)ferrocene Properties

Melting point 181-182°C (dec.)
storage temp. Inert atmosphere,Room Temperature
form crystal
color orange to red
Water Solubility Insoluble in water.
InChI InChI=1S/2C13H22P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-10H,1-6H3;
InChIKey FPLSJBJGQLJLSV-UHFFFAOYSA-N
SMILES P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:9,10,11,12,13,23,24,25,26,27|

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-36/37/39-26
WGK Germany  3
TSCA  No
HS Code  29319090
NFPA 704
1
2 0

1,1'-Bis(di-tert-butylphosphino)ferrocene price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 695149 1,1′-Bis(di-tert-butylphosphino)ferrocene 84680-95-5 1g $171 2024-03-01 Buy
Sigma-Aldrich 695149 1,1′-Bis(di-tert-butylphosphino)ferrocene 84680-95-5 250mg $93.8 2023-06-20 Buy
TCI Chemical B2711 1,1'-Bis(di-tert-butylphosphino)ferrocene >95.0%(T) 84680-95-5 1g $124 2024-03-01 Buy
TCI Chemical B2711 1,1'-Bis(di-tert-butylphosphino)ferrocene >95.0%(T) 84680-95-5 100mg $23 2024-03-01 Buy
Alfa Aesar L19759 1,1'-Bis(di-tert-butylphosphino)ferrocene, 98% 84680-95-5 500mg $65.2 2021-12-16 Buy
Product number Packaging Price Buy
695149 1g $171 Buy
695149 250mg $93.8 Buy
B2711 1g $124 Buy
B2711 100mg $23 Buy
L19759 500mg $65.2 Buy

1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties,Uses,Production

Reaction

  1. Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
  2. Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
  3. Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
  4. Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
  5. Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
  6. Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
  7. Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
  8. Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
  9. Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.
Reactions of 84680-95-5_1
Reactions of 84680-95-5_2

Uses

1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.

Uses

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.

65587-59-9
13716-10-4
84680-95-5
Synthesis of 1,1'-Bis(di-tert-butylphosphino)ferrocene from Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy- and Di-tert-butylchlorophosphane
Global( 264)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Research New Materials Co., Ltd. 		+8618903931531 sales018@researchvip.com China 179 58
Puyang Huicheng Electronic Materials Co., Ltd.
+86-0393-+86-0393-8910800 +8615839383373 info@huichengchem.com China 529 58
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 403 58
Hebei Weibang Biotechnology Co., Ltd 		+8615531157085 abby@weibangbio.com China 8810 58
Hebei Mojin Biotechnology Co., Ltd 		+86 13288715578 +8613288715578 sales@hbmojin.com China 12835 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718 +86-13336195806 sales@capot.com China 29791 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 18751 58
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32957 60
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29880 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28172 58

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View Lastest Price from 1,1'-Bis(di-tert-butylphosphino)ferrocene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,1'-Bis(di-tert-butylphosphino)ferrocene pictures 2024-12-17 1,1'-Bis(di-tert-butylphosphino)ferrocene
84680-95-5
 US $0.00-0.00 / KG 1KG 0.98 500kg XINXIANG RUNYU MATERIAL CO., LTD.
1,1'-Bis(di-tert-butylphosphino)ferrocene pictures 2024-11-26 1,1'-Bis(di-tert-butylphosphino)ferrocene
84680-95-5
 US $0.00 / g 500g 98％ 10 Henan Research New Materials Co., Ltd.
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE pictures 2024-11-11 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
84680-95-5
 US $0.00-0.00 / KG 1KG 99% 20 mt Hebei Weibang Biotechnology Co., Ltd
BIS[(DI-TERT-BUTYLPHOSPHINO)CYCLOPENTADIENYL]IRON 1,1'-Bis(di-t-butylphosphino)ferrocene,min.98% 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE 1,1'-Bis(di-tert-butylphosphino)ferrocene,min. 98% 1,1'-Bis(di-tert-butylphosphino)ferrocene ,98% 1,1'-Bis(di-tert-butylphosphin 98% DtBPF 1,1'-Bis(di-tert-butylphosphiNA)ferrocene 1,1'-Bis[bis(1,1-diMethylethyl)phosphino]ferrocene 1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% 1,1'-Bis(di-t-butylphosphino)ferrocene,98% DtBPF DBtPF 1,1'-Bis(di-t-butylphosphino)ferrocene,DtBPF 1,1'-Bis(di-tert-butylphosphino)ferrocene > 1,1'-Bis(di-t-butyL 1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF 1,1'-Bis(di-tert-butylphosphi DTBPF / 1,1'-Bis(di-tert-butylphosphino)ferrocene 1,1'-Bis(di-tert-butylphosphino)ferrocene 98% DTBPF 1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE Dehch（bis(2-ethylhexyl) cyclohexane -1,2-dicarboxylate） 1,1'-Bis(di-tert-butylphosphino)ferrocene 1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene 1,1'-Bis(di-t-butylphosphino)ferrocene 84680-95-5 94680-95-5 C26H44FeP2 C4H92PC5H42Fe 2C13H22PFe C26H44FeP210 2C13H23PFe C26H42FeP2 Metallocenes Transition Metal Compounds Phosphine Ligands Classes of Metal Compounds Ferrocenes Fe (Iron) Compounds Achiral Phosphine Aryl Phosphine Classes of Metal Compounds Fe (Iron) Compounds Ferrocenes Metallocenes Phosphine Ligands Synthetic Organic Chemistry Transition Metal Compounds Catalysis and Inorganic Chemistry Phosphorus Compounds Polydentate Phosphine Ligands