[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- CAS No.
- 72287-26-4
- Chemical Name:
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
- Synonyms
- PDCL2(DPPF);(dppf)2PdCl2;dichloropalladiuM;1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2;oropaL;[1,1′(DPPF)PdCl2;JACS-72287-26-4;CHEMWISH IC30255
- CBNumber:
- CB3276259
- Molecular Formula:
- C34H28Cl2FeP2Pd
- Molecular Weight:
- 731.7
- MDL Number:
- MFCD00015757
- MOL File:
- 72287-26-4.mol
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H315-H319-H335 |
Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a |
Hazard Codes | Xn,Xi |
Risk Statements | 20/21/22-36/37/38-40 |
Safety Statements | 23-24/25-26-36/37 |
WGK Germany | 3 |
TSCA | No |
HazardClass | IRRITANT |
HS Code | 28439000 |
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) price More Price(37)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 697230 | [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) | 72287-26-4 | 1g | $74.3 | 2024-03-01 | Buy |
Sigma-Aldrich | 697230 | [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) | 72287-26-4 | 5g | $227 | 2024-03-01 | Buy |
Alfa Aesar | 046503 | Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), Pd 13.5-15.5% | 72287-26-4 | 1g | $72.5 | 2023-06-20 | Buy |
Sigma-Aldrich | 697230 | [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) | 72287-26-4 | 250g | $9580 | 2024-03-01 | Buy |
TRC | B430465 | [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) | 72287-26-4 | 1g | $100 | 2021-12-16 | Buy |
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties,Uses,Production
Uses
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds.Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.
Chemical Properties
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid
Uses
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.
Uses
suzuki reaction
Uses
Catalyst for C-C and C-N coupling reaction.
Application
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
Mechanism of action
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.
R = usually sp2
hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Preparation Products And Raw materials
Raw materials
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Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Wuhan Huahan Dingcheng New Material Technology Co., Ltd | +undefined-027-81388558 +undefined086-1878077615 | huahandingcheng@sina.com | China | 342 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8810 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5857 | 58 |
Henan Bao Enluo International TradeCo.,LTD | +86-17331933971 +86-17331933971 | deasea125996@gmail.com | China | 2472 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20284 | 58 |
Capot Chemical Co.,Ltd. | +86-(0)57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18751 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
Hangzhou FandaChem Co.,Ltd. | +8615858145714 | FandaChem@Gmail.com | China | 9095 | 55 |
Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
View Lastest Price from [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-12-12 | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
|
US $80.00 / kilograms | 10kilograms | 99 | 10 | Hebei Dangtong Import and export Co LTD | ||
2024-11-29 | [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
|
US $10.00 / KG | 100KG | 99% | 100 mt | Hebei Weibang Biotechnology Co., Ltd | ||
2024-11-12 | 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II) dichloride
72287-26-4
|
US $1250.00 / g | 1g | 99 % | 500 Kg | R&D Scientific Inc. |
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
- US $80.00 / kilograms
- 99
- Hebei Dangtong Import and export Co LTD
- [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
- US $10.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
- 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II) dichloride
72287-26-4
- US $1250.00 / g
- 99 %
- R&D Scientific Inc.
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