Glycidyl methacrylate
- CAS No.
- 106-91-2
- Chemical Name:
- Glycidyl methacrylate
- Synonyms
- 2,3-EPOXYPROPYL METHACRYLATE;oxiran-2-ylmethyl methacrylate;Glycidyl methacylate;2-Propenoicacid,2-methyl-,oxiranylmethylester;cp105;sr379;CP 105;SR-379;blemmerg;blemmergma
- CBNumber:
- CB3258080
- Molecular Formula:
- C7H10O3
- Molecular Weight:
- 142.15
- MDL Number:
- MFCD00005137
- MOL File:
- 106-91-2.mol
- MSDS File:
- SDS
| Melting point | -52°C |
|---|---|
| Boiling point | 189 °C(lit.) |
| Density | 1.075 g/mL at 20 °C |
| vapor pressure | 4.2hPa at 25℃ |
| refractive index |
n |
| Flash point | 169 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Liquid |
| color | Clear |
| Viscosity | 5 cp (25C) |
| Water Solubility | 0.5-1.0 g/100 mL at 20 ºC |
| BRN | 2506 |
| Stability | Unstable. Light sensitive. May be stabilized with around 100ppm MEHQ. Refrigerate. |
| InChIKey | VOZRXNHHFUQHIL-UHFFFAOYSA-N |
| LogP | 0.96 at 25℃ |
| CAS DataBase Reference | 106-91-2(CAS DataBase Reference) |
| Indirect Additives used in Food Contact Substances | GLYCIDYL METHACRYLATE |
| FDA 21 CFR | 175.105; 176.180 |
| EWG's Food Scores | 5 |
| FDA UNII | R8WN29J8VF |
| IARC | 2A (Vol. 125) In prep. |
| NIST Chemistry Reference | 2-Propenoic acid, 2-methyl-, oxiranylmethyl ester(106-91-2) |
| EPA Substance Registry System | Glycidyl methacrylate (106-91-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS05,GHS06,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H302-H311-H314-H317-H335-H341-H350-H360F-H372 | |||||||||
| Precautionary statements | P202-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,T,T+ | |||||||||
| Risk Statements | 20/21/22-36/38-43-60-45-68-39/26-34 | |||||||||
| Safety Statements | 26-28-28A-45-36/37-53-36/37/39 | |||||||||
| RIDADR | UN 2810 6.1/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | OZ4375000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29161490 | |||||||||
| Hazardous Substances Data | 106-91-2(Hazardous Substances Data) | |||||||||
| Toxicity | dog,LCLo,inhalation,1400mg/m3/6H (1400mg/m3),LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,National Technical Information Service. Vol. OTS0530684, | |||||||||
| NFPA 704 |
|
Glycidyl methacrylate price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 151238 | Glycidyl methacrylate 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor | 106-91-2 | 100g | $49 | 2024-03-01 | Buy |
| Sigma-Aldrich | 151238 | Glycidyl methacrylate 97%, contains 100 ppm monomethyl ether hydroquinone as inhibitor | 106-91-2 | 5kg | $708 | 2024-03-01 | Buy |
| TCI Chemical | M0590 | Glycidyl Methacrylate (stabilized with MEHQ) >95.0%(GC) | 106-91-2 | 25g | $30 | 2024-03-01 | Buy |
| TCI Chemical | M0590 | Glycidyl Methacrylate (stabilized with MEHQ) >95.0%(GC) | 106-91-2 | 500g | $104 | 2024-03-01 | Buy |
| Alfa Aesar | L11133 | Glycidyl methacrylate, 97%, stab. with 100ppm 4-methoxyphenol | 106-91-2 | 50g | $34.4 | 2024-03-01 | Buy |
Glycidyl methacrylate Chemical Properties,Uses,Production
Description
Glycidyl Methacrylate (GMA) is a clear, colorless liquid with a potent ester and fruity odor. It comprises a polymerizable methacrylate functional group on one end and a reactive epoxy group on the other. It is slightly miscible with water, soluble in most organic solvents, and has relatively low volatility. Its vapor is heavier than air. It copolymerizes readily with various functional groups, such as phenols, ketones, acids, and amines. The added epoxy group imparts durability, mechanical strength, optical transparency, and adhesiveness.
Chemical Properties
Glycidyl methacrylate (GMA) is a colorless liquid with a fruity odor. Floats on water. (USCG, 1999)
Glycidyl methacrylate is a polyfunctional monomer. It acts as an adhesion promoting crosslinking co-monomer for acrylic and vinyl resins. It is also a reactive colorless diluent. GMA is soluble in ethanol, acetone, diethyl ether, benzene.
Uses
Glycidyl methacrylate is commonly used as a monomer for the preparation of epoxy resins. It is also used to provide epoxy functionalization to polyolefins and other acrylate resins. Further, it is also useful as an epoxy resin additive for paint coating formulations and adhesive applications.
Uses
Glycidyl methacrylate (GMA) is a common monomer used in the creation of epoxy resins. It is used to provide epoxy functionalization to polyolefins and other acrylate resins.
Glycidyl methacrylate is used in the production of polymer coatings and finishes, adhesives, plastics and elastomers.
Glycidyl methacrylate dextran has been reported to be used as a biocompatible hydrogel. In situ polymerization of GMA with trimethylolpropane trimethacrylate to form macroporous sorbents has also been reported. GMA may also be grafted onto polypropylene.
Preparation
Glycidyl methacrylate is produced from methacrylic acid and glycidol. Glycidol contain both epoxide and alcohol functional groups.It is an enoate ester and an epoxide. It derives from a methacrylic acid and a glycidol.
Definition
ChEBI: Glycidyl methacrylate is an enoate ester obtained by formal condensation of the carboxy group of methacrylic acid with the hydroxy group of glycidol. It is an enoate ester and an epoxide. It is functionally related to a methacrylic acid and a glycidol.
Reactions
Glycidyl methacrylate (GMA) is a kind of functional monomer. Its active vinyl and epoxy groups could be grafted with polyolefin and reacted with the polar groups such as amine, hydroxyl and carboxyl group, respectively. It can also undergo polymerization to form poly (glycidyl methacrylate).
Synthesis Reference(s)
Tetrahedron, 48, p. 5099, 1992 DOI: 10.1016/S0040-4020(01)90120-6
Synthesis, p. 1019, 1986 DOI: 10.1055/s-1986-31856
General Description
Colorless liquid with a fruity odor. Floats on water.
Air & Water Reactions
Flammable. Slightly water soluble.
Reactivity Profile
Epoxides, such as Glycidyl methacrylate, are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
Health Hazard
The liquid irritates eyes about as much as soap. Prolonged contact with skin produces irritation and dermatitis.
Fire Hazard
Special Hazards of Combustion Products: Irritating vapors are generated when heated
Flammability and Explosibility
Flammable
Glycidyl methacrylate Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Qingdao RENAS Polymer Material Co., Ltd. | +86-0532-86867058 +86-18562606086 | sales@qdrenas.com | China | 476 | 58 |
| Yancheng Green Chemicals Co.,Ltd | +undefined-86-25-86655873 | info@royal-chem.com | China | 114 | 58 |
| Anhui Royal Chemical Co., Ltd. | +86-25-86655873 +8613962173137 | marketing@royal-chem.com | China | 193 | 55 |
| Qingdao Zhongke Huatai Industrail Co., Ltd. | +86-532-86898076 +86-15153292017 | zkhtchem@163.com | China | 25 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8810 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12835 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5857 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5889 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18151 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20284 | 58 |
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View Lastest Price from Glycidyl methacrylate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-12-22 | Glycidyl methacrylate
106-91-2
|
US $99.00-66.00 / kg | 0.0010000000474974513kg | 99% | 5000 | HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | |
 |
2024-12-20 | Glycidyl methacrylate
106-91-2
|
US $5.00 / KG | 1KG | ≥99% | 1000mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2024-12-20 | Glycidyl Methacrylate
106-91-2
|
US $120.00-65.00 / kg | 1kg | 99% | 20ton | Hebei Zhuanglai Chemical Trading Co.,Ltd |
-
- Glycidyl methacrylate
106-91-2
- US $99.00-66.00 / kg
- 99%
- HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
-
- Glycidyl methacrylate
106-91-2
- US $5.00 / KG
- ≥99%
- Jinan Finer Chemical Co., Ltd
-
- Glycidyl Methacrylate
106-91-2
- US $120.00-65.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co.,Ltd