ChemicalBook >> CAS DataBase List >>4,4'-Bipyridine
4,4'-Bipyridine
- CAS No.
- 553-26-4
- Chemical Name:
- 4,4'-Bipyridine
- Synonyms
- 4,4-BIPYRIDINE;4,4-DIPYRIDYL;4,4'-BIPYRIDYL;4,4'-DIPYRIDYL;GAMMA,GAMMA-DIPYRIDYL;'LGC' (1608);γ,γ'-Dipyridy;g,g'-Dipyridyl;4,4'-Bipyridyl;4,4'-Dipyridyl
- CBNumber:
- CB1671180
- Molecular Formula:
- C10H8N2
- Molecular Weight:
- 156.18
- MDL Number:
- MFCD00006416
- MOL File:
- 553-26-4.mol
- MSDS File:
- SDS
Last updated:2024-12-18 14:15:30
| Melting point | 109-112 °C(lit.) |
|---|---|
| Boiling point | 305 °C(lit.) |
| Density | 1.2814 (rough estimate) |
| refractive index | 1.6057 (estimate) |
| Flash point | 304-305°C |
| storage temp. | Store below +30°C. |
| solubility | 4.5g/l |
| form | Powder |
| pka | pK1:3.17(+2);pK2:4.82(+1) (25°C) |
| color | Off-white to beige |
| Water Solubility | slightly soluble |
| Sensitive | Hygroscopic |
| λmax | 300nm(CH3CN)(lit.) |
| Merck | 14,3348 |
| BRN | 113176 |
| Stability | Stable. Incompatible with strong oxidizing agents, strong acids. |
| InChIKey | MWVTWFVJZLCBMC-UHFFFAOYSA-N |
| CAS DataBase Reference | 553-26-4(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | X4O2OD61CB |
| NIST Chemistry Reference | |
| EPA Substance Registry System |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301 | |||||||||
| Precautionary statements | P301+P310+P330 | |||||||||
| Hazard Codes | T,Xi | |||||||||
| Risk Statements | 25-36/37/38-20/21-23/24/25 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 2811 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | DW1760000 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29333999 | |||||||||
| Toxicity | LD50 orally in Rabbit: 172 mg/kg | |||||||||
| NFPA 704 |
|
4,4'-Bipyridine price More Price(31)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 289426 | 4,4′?Dipyridyl 98% | 553-26-4 | 5g | $38.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.20158 | 4,4′-Bipyridine for synthesis | 553-26-4 | 10g | $75.7 | 2024-03-01 | Buy |
| Sigma-Aldrich | 289426 | 4,4′?Dipyridyl 98% | 553-26-4 | 25g | $126 | 2024-03-01 | Buy |
| TCI Chemical | B0469 | 4,4'-Bipyridyl >98.0%(GC)(T) | 553-26-4 | 25g | $83 | 2024-03-01 | Buy |
| TCI Chemical | B0469 | 4,4'-Bipyridyl >98.0%(GC)(T) | 553-26-4 | 100g | $252 | 2024-03-01 | Buy |
4,4'-Bipyridine Chemical Properties,Uses,Production
Chemical Properties
off-white to tan powder
Uses
4,4'-Bipyridine is used in transition-metal complex catalyst chemistry for uniform polymerization, in luminescence chemistry and in spectrophotometric analysis. It plays an important role as a photosensitizer and luminescent material. It is also used as a precursor to paraquat viz. N,N'-dimethyl-4,4'-bipyridinium.
Definition
ChEBI: A bipyridine in which the two pyridine moieties are linked by a bond between positions C-4 and C-4'.
Synthesis Reference(s)
Tetrahedron Letters, 26, p. 1655, 1985 DOI: 10.1016/S0040-4039(00)98576-9
General Description
4,4′-Dipyridyl (BPY) is an organic linker mainly used in the preparation of coordination polymers. It is a pyridine derivative in which pyridyl groups can rotate along the carbon-carbon structure. It can be used as a catalyst for photoelectrochemical reduction.
Safety Profile
Poison by ingestion. When heatedto decomposition it emits toxic vapors of NOx.
Purification Methods
It crystallises from water, *benzene/pet ether, ethyl acetate and sublimes in vacuo at 70o. Also purify it by dissolving in 0.1M H2SO4 and twice precipitating by addition of 1M NaOH to pH 8. Then recrystallise it from EtOH. For the dihydrochloride see Viologen below. [Collman et al. J Am Chem Soc 109 4606 1987, Beilstein 23 H 800, 23 III/IV 1371, 23/8 V 28.]
4,4'-Bipyridine Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of2
Global( 508)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Yongzeng Technology Co.,Ltd | +86-021-65281118 +86-13818947575 | sales@yongzchem.com | China | 138 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8810 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12835 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5857 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 7629 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8617732866630 | bess@weibangbio.com | China | 18151 | 58 |
| airuikechemical co., ltd. | +undefined86-15315557071 | sales02@sdzhonghuimaterial.com | China | 983 | 58 |
| Hebei Saisier Technology Co., LTD | +86-18400010335 +86-18034520335 | admin@hbsaisier.cn | China | 1015 | 58 |
| Hebei Longbang Technology Co., LTD | +86-18633929156 +86-18633929156 | admin@hblongbang.com | China | 941 | 58 |
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
View Lastest Price from 4,4'-Bipyridine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-12-19 | 4,4'-Bipyridine
553-26-4
|
US $5.00 / KG | 1KG | 99% | 20TONS | Hebei Longbang Technology Co., Ltd | |
 |
2024-11-28 | 4,4'-Bipyridine
553-26-4
|
US $8.90 / KG | 1KG | 99% | 10 mt | Hebei Weibang Biotechnology Co., Ltd | |
 |
2024-11-07 | 4,4'-Bipyridine
553-26-4
|
US $0.00 / kg | 1kg | 99% | 1000000 | Hebei Jingbo New Material Technology Co., Ltd |
-
- 4,4'-Bipyridine
553-26-4
- US $5.00 / KG
- 99%
- Hebei Longbang Technology Co., Ltd
-
- 4,4'-Bipyridine
553-26-4
- US $8.90 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
-
- 4,4'-Bipyridine
553-26-4
- US $0.00 / kg
- 99%
- Hebei Jingbo New Material Technology Co., Ltd
553-26-4(4,4'-Bipyridine)Related Search:
Pyridine
4-Aminobutyric acid
DIPIPERIDINOMETHANE
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
Sulfasalazine
Chromium picolinate
2,2'-Bipyridine
Morfamquat(dichloride((content>65%)
Paraquat methosulfate
2,2':6',2''-TERPYRIDINE
1of4
4,4’-Bipyridine,dihydrate
Bipyridine, 4,4'-
gamma,gamma’-bipyridyl
gamma,gamma'-Bipyridyl
4,4'Bipyridinyl
4,4'-BIPYRIDINE ANHYDROUS PESTANAL
4,4'-Bipyridyl,98%
4,4'-Bipyridine,98%
4,4'-BIPYRIDINE ANHYDROUS
4,4'-Dipyridyl, anhydrous, 98%
4,4-DIPYRIDYL, 4,4-BIPYRIDINE
4,4''-DIPYRIDINE / 4,4''-DIPYRIDYL
4,4''-DIPYRIDYL, 98%, ANHYDROUS
4,4μ-Bipyridine, 4,4μ-Bipyridyl
4,4'-Dipyridyl ,99%
g,g'-Dipyridyl
4,4′-Bipyridyl,4,4′-Bipyridine
4,4'-Bipyridyl dihydrate
4,4'-Dipyridyl 98%
4, 4 - al pyridine
4,4'-Bipyridine SynonyMs 4,4'-Dipyridyl
γ,γ'-Dipyridy
4,4'-Dipyridyl≥ 99% (Assay)
4,4'-Bipyridine for synthesis
'LGC' (1608)
GAMMA,GAMMA'-DIPYRIDYL
4, 4'-DIPYRIDINE
4,4'-BIPYRIDINE
4,4'-BIPYRIDYL HYDRATE
4,4,4'-DIPYRIDYL
4-PYRIDIN-4-YLPYRIDINE
4-(4-Pyridyl)pyridine
4,4'-Dipyridyl, 99%, for synthesis
4,4'-Bipyridyl >
4, 4 '- pyridine
4,4,-Bipyridyl, GR 98%
4,4-DIPYRIDYL
4,4-BIPYRIDINE
GAMMA,GAMMA-DIPYRIDYL
4,4'-BIPYRIDYL
4,4'-DIPYRIDYL
4,4'-Bipyridine (8CI, 9CI, ACI)
Metamitron Impurity 7
4,4'-Bipyridine
4,4'-Bipyridyl
4,4'-Dipyridine
4,4'-Dipyridyl
553-26-4
53-26-4
-C5H4N22H2O
Photochromic Compounds
Viologens (Photochromic, Related Compounds)
C9
C9 to C46
Carbonyl Compounds
Building Blocks
Pyridines
Ketones