ChemicalBook >> CAS DataBase List >>4-Carboxyphenylboronic acid
4-Carboxyphenylboronic acid
- CAS No.
- 14047-29-1
- Chemical Name:
- 4-Carboxyphenylboronic acid
- Synonyms
- 4-BORONOBENZOIC ACID;4-borono-benzoicaci;4-Carboxyphenylboronic;4-Carboxyphenylboronic acid, 97% 5GR;NSC 221170;AURORA 14935;AKOS BRN-0008;WLN: VHOR DBQQ;4-CarboxyphenyL;ZERENEX ZX001647
- CBNumber:
- CB1312607
- Molecular Formula:
- C7H7BO4
- Molecular Weight:
- 165.94
- MDL Number:
- MFCD00151801
- MOL File:
- 14047-29-1.mol
- MSDS File:
- SDS
Last updated:2024-12-06 22:41:32
| Melting point | 220 °C (dec.) (lit.) |
|---|---|
| Boiling point | 406.4±47.0 °C(Predicted) |
| Density | 1.40±0.1 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | DMSO (Slightly), Methanol (Slightly), Water (Slightly) |
| form | Powder |
| pka | 4.08±0.10(Predicted) |
| color | Off-white to light beige |
| BRN | 3031088 |
| InChI | InChI=1S/C7H7BO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,11-12H,(H,9,10) |
| InChIKey | SIAVMDKGVRXFAX-UHFFFAOYSA-N |
| SMILES | C(O)(=O)C1=CC=C(B(O)O)C=C1 |
| CAS DataBase Reference | 14047-29-1(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | XQQ1T11DYK |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H303-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313 | |||||||||
| Hazard Codes | Xi,Xn | |||||||||
| Risk Statements | 36/37/38-20/21/22 | |||||||||
| Safety Statements | 37/39-26-36 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | CY8925000 | |||||||||
| TSCA | No | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
4-Carboxyphenylboronic acid price More Price(48)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 456772 | 4-Carboxyphenylboronic acid | 14047-29-1 | 1g | $42.1 | 2024-03-01 | Buy |
| Sigma-Aldrich | 456772 | 4-Carboxyphenylboronic acid | 14047-29-1 | 10g | $363 | 2024-03-01 | Buy |
| TCI Chemical | C1353 | 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) | 14047-29-1 | 1g | $33 | 2024-03-01 | Buy |
| TCI Chemical | C1353 | 4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride) | 14047-29-1 | 5g | $99 | 2024-03-01 | Buy |
| Alfa Aesar | B20954 | 4-Carboxybenzeneboronic acid, 97% | 14047-29-1 | 1g | $33.65 | 2024-03-01 | Buy |
4-Carboxyphenylboronic acid Chemical Properties,Uses,Production
Description
4-Carboxyphenylboronic acid is a highly versatile reagent. It is a reagent used in various reactions including condensation reactions with stabilizer chains at the surface of polystyrene latex, Suzuki coupling reactions, esterification, derivatization of polyvinylamine, synthesis of isotopically labeled mercury and functionalization of poly-SiNW for detection of dopamine. It is reagents used for Suzuki-Miyaura cross-coupling, induction of pH sensitivity on fluorescence lifetime of quantum dots by NIR fluorescent dyes, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Chan-Lam-type Copper (Cu)-catalyzed S-arylation with aryl boronic acids at room temperature. It is reagents used for the preparation of isoquinolones via regioselective Suzuki-Miyaura cross-coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation, amprenavir-based P1-substituted bi-aryl derivatives as ultra-potent HIV-1 protease inhibitors, phenols via visible-light initiated aerobic oxidative hydroxylation of arylboronic acids using air as oxidant catalyzed by Ruthenium (Ru)-complex, glucose sensitive boronic acid-bearing block copolymers, trisulfonated calixarene upper-rim sulfonamido derivatives and their complexation with the trimethyllysine epigenetic mark. It can also be used as a corrosion inhibitor for steel.
Reference
- Nam, N. D., et al. "A study of 4-carboxyphenylboronic acid as a corrosion inhibitor for steel in carbon dioxide containing environments." Corrosion Science 76.10(2013):257-266.
- Vollmueller, Frank, et al. "Cyclization of 4-carboxyphenylboronic acid with hydrazide derivative; hydrolysis; catalytic esterification." US, US 6197967 B1. 2001.
Chemical Properties
Off-white to light beige powder
Uses
Intermediates of Liquid Crystals
Uses
suzuki reaction
Uses
4-Carboxyphenylboronic acid is a reagent used in suzuki coupling reactions.
4-Carboxyphenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
4-(PIPERIDINE-1-CARBONYL)PHENYLBORONIC ACID
4-(2-CYANOETHYLAMINOCARBONYL)PHENYLBORONIC ACID
4-Carbamoylphenylboronic acid
4-AZIDOBENZOIC ACID
4-(1H-PYRAZOL-4-YL)BENZOIC ACID
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Global( 570)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Maison Chemical Co.,Ltd. | +8615511852758 | sales@maisonchem.com.cn | China | 484 | 58 |
| Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8810 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12835 | 58 |
| Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 7629 | 58 |
| Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 | sales1@chuanghaibio.com | China | 5889 | 58 |
| Anhui Ruihan Technology Co., Ltd | +8617756083858 | daisy@anhuiruihan.com | China | 973 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20284 | 58 |
| HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | +8615350851019 | admin@86-ss.com | China | 1001 | 58 |
| Hebei Zhuanglai Chemical Trading Co Ltd | +86-16264648883 +86-16264648883 | niki@zlchemi.com | China | 2691 | 58 |
| Frapp's ChemicalNFTZ Co., Ltd. | +86 (576) 8169-6106 | sales@frappschem.com | China | 880 | 50 |
View Lastest Price from 4-Carboxyphenylboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-12-22 | 4-Carboxyphenylboronic acid
14047-29-1
|
US $99.00-80.00 / ton | 1ton | 99% | 5000 | HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | |
 |
2024-12-20 | 4-Carboxyphenylboronic acid
14047-29-1
|
US $10.00 / kg | 1kg | 99% | 20 ton | Hebei Zhuanglai Chemical Trading Co Ltd | |
 |
2024-12-02 | 4-Carboxyphenylboronic acid
14047-29-1
|
US $10.00 / KG | 1KG | 99% | 5tons | Hebei Weibang Biotechnology Co., Ltd |
-
- 4-Carboxyphenylboronic acid
14047-29-1
- US $99.00-80.00 / ton
- 99%
- HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
-
- 4-Carboxyphenylboronic acid
14047-29-1
- US $10.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co Ltd
-
- 4-Carboxyphenylboronic acid
14047-29-1
- US $10.00 / KG
- 99%
- Hebei Weibang Biotechnology Co., Ltd
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1of4
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4-DIHYDROXYBORANYL-BENZOIC ACID
4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)
4-Carboxyphenylboronic acid, 98%, for synthesis
4-CarboxyphenyL
4-Carboxyphenylboronicaci
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4-Carboxyphenylboronic
13C6]-4-Boronobenzoic acid
14047-29-1