| Identification | Back Directory | [Name]
4-Chloro-6-methoxy-2-(methylthio)pyrimidine | [CAS]
89466-42-2 | [Synonyms]
4-Chloro-6-methoxy-2-(methylthio)
6-methoxy-2-methylthio-4-chlorpyrimidine
4-CHLORO-6-METHOXY-2-(METHYLTHIO)PYRIMIDINE
Pyrimidine, 4-chloro-6-methoxy-2-(methylthio)-
4-Chloro-6-methoxy-2-(methylthio)pyrimidine ,98% | [EINECS(EC#)]
604-604-1 | [Molecular Formula]
C6H7ClN2OS | [MDL Number]
MFCD10574952 | [MOL File]
89466-42-2.mol | [Molecular Weight]
190.65 |
| Chemical Properties | Back Directory | [Melting point ]
38-39℃ | [Boiling point ]
288℃ | [density ]
1.36 | [refractive index ]
1. | [Fp ]
128℃ | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [pka]
-2.26±0.30(Predicted) | [InChI]
InChI=1S/C6H7ClN2OS/c1-10-5-3-4(7)8-6(9-5)11-2/h3H,1-2H3 | [InChIKey]
FNYLFWGITLMOHA-UHFFFAOYSA-N | [SMILES]
C1(SC)=NC(OC)=CC(Cl)=N1 |
| Hazard Information | Back Directory | [Chemical Properties]
White solid | [Uses]
4-chloro-6-methoxy-2-(methylthio)pyrimidine is a versatile scaffold and can undergo Suzuki-Miyaura coupling to afford 4-aryl-6-methoxy-2-(methylthio)pyrimidines, as well as amine or alcohol displacement of the chloride, oxidation to sulfone, and condensation reactions to give polycyclic systems][1].
| [References]
[1] A. Kalogirou, P. Koutentis. “4-Chloro-6-ethoxy-2-(methylthio)pyrimidine.” Molbank 2017 1 (2016). |
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