| Identification | Back Directory | [Name]
hexafluorophosphate | [CAS]
870987-63-6 | [Synonyms]
Ir[dF(CF3)ppy]2(dtbbpy)PF6
4-tert-butyl-2-(4-tert-butyl-2-pyridyl)pyridine
bis[3,5-Difluoro-2-[5-(trifluoromethyl)-2-pyridyl]phenyl]ruthenium(1+)
(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate | [Molecular Formula]
C42H34F16IrN4P | [MDL Number]
MFCD27952556 | [MOL File]
870987-63-6.mol | [Molecular Weight]
144.964 |
| Questions And Answer | Back Directory | [Reaction]
- Visible light photoredox-catalyzed cascade cyclizations of α-bromochalcones or α-bromocinnamates with heteroarenes.
- Enantioselective α-benzylation of aldehydes via photoredox organocatalysis.
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| Hazard Information | Back Directory | [Uses]
(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles. | [reaction suitability]
core: iridium
reagent type: catalyst
reaction type: Photocatalysis |
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