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ChemicalBook--->CAS DataBase List--->7688-21-3

7688-21-3

7688-21-3 Structure

7688-21-3 Structure
IdentificationBack Directory
[Name]

CIS-2-HEXENE
[CAS]

7688-21-3
[Synonyms]

(Z)-2-C6H12
(Z)-2-Hexene
CIS-2-HEXENE
(Z)-hex-2-ene
(2Z)-2-Hexene
cis-hex-2-ene
2-Hexene, cis-
cis-2-Hexene,95%
cis-2-Hexene 95%
cis-2-Hexene
[EINECS(EC#)]

231-697-1
[Molecular Formula]

C6H12
[MDL Number]

MFCD00066520
[MOL File]

7688-21-3.mol
[Molecular Weight]

84.16
Chemical PropertiesBack Directory
[Appearance]

Clear colorless liquid
[Melting point ]

-141.15°C
[Boiling point ]

68-70 °C(lit.)
[density ]

0.669 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.396(lit.)
[Fp ]

−5 °F
[storage temp. ]

Refrigerator (+4°C) + Flammables area
[form ]

Liquid
[color ]

Clear colorless
[Specific Gravity]

0.684
[Water Solubility ]

Immiscible in water.
[BRN ]

1719019
[LogP]

3.420 (est)
[CAS DataBase Reference]

7688-21-3
[EPA Substance Registry System]

cis-2-Hexene (7688-21-3)
Hazard InformationBack Directory
[Chemical Properties]

Clear colorless liquid
[Uses]

cis-2-Hexene is used as an organic chemical synthesis intermediate.
[General Description]

cis-2-Hexene is one of the isomeric forms of hexene. It is obtained from 2-hexyne, via semihydrogenation in the presence of Pd78(phen) [phen = 1,10-Phenanthroline] on titanium dioxide in n-octane. cis-2-Hexene is formed as one of the primary product from the dimerization of propylene in the presence of a nickel oxide-silica-alumina catalyst. It undergoes isomerization/hydrosilylation reaction with phenyl silane in the presence of cobalt catalyst to afford 1-hexylphenylsilane.
[Purification Methods]

Purify it as for 1-hexene above. [Beilstein 1 IV 833.]
Safety DataBack Directory
[Hazard Codes ]

F,Xi
[Risk Statements ]

11-36/37/38
[Safety Statements ]

16-26-36
[RIDADR ]

UN 3295 3/PG 2
[WGK Germany ]

3
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29012900
Spectrum DetailBack Directory
[Spectrum Detail]

CIS-2-HEXENE(7688-21-3)13CNMR
CIS-2-HEXENE(7688-21-3)IR
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