Identification | Back Directory | [Name]
(2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE | [CAS]
74839-84-2 | [Synonyms]
(R,R)-CHIRAPHOS (R,R)-Chiraphos,97% 2,3-Bis(diphenylphosphino)butane (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE (2R,3R)-(+)-2,3-BIS(DIPHENYL PHOSPHINO)BUTANE (2R,3R)-Butane-2,3-diylbis(diphenylphosphine) (2R,3R)-(+)-Bis(diphenylphosphino)butane, (R,R)-CHIRAPHOS (2R,3R)-(+)-Bis(diphenylphosphino)butane, 98% (R,R)-CHIRAPHOS (2R,3R)-(+)-2,3-Bis(diphenylphosphino)butane (R,R)-CHIRAPHOS | [Molecular Formula]
C28H28P2 | [MDL Number]
MFCD00075403 | [MOL File]
74839-84-2.mol | [Molecular Weight]
426.47 |
Chemical Properties | Back Directory | [Appearance]
white crystalline powder | [Melting point ]
104-109 °C
| [Boiling point ]
529.2±33.0 °C(Predicted) | [storage temp. ]
Inert atmosphere,2-8°C | [form ]
solid | [color ]
white | [Sensitive ]
Air Sensitive | [CAS DataBase Reference]
74839-84-2 |
Hazard Information | Back Directory | [Chemical Properties]
white crystalline powder | [Uses]
(2R,3R)-Bis(diphenylphosphino)butane is a reagent used in the synthesis of endothelin A receptor antagonists. Also used in the synthesis of (R)-Tolterodine and (S)-Tolterodine. | [Purification Methods]
It recrystallises from absolute EtOH (~6g in 60mL) as colourless plates [Fryzuk & Bosnich J Am Chem Soc 99 6262 1977, Fryzuk & Bosnich J Am Chem Soc 101 3043 1979]. |
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