| Identification | Back Directory | [Name]
Hydrazine acetate | [CAS]
7335-65-1 | [Synonyms]
HYDRAZINE ACETATE
hydrazinyl acetate
hydrazinium acetate
Hydrazine acetate,99%
Hydrazine acetate 97%
HYDRAZINE MONOACETATE
HYDRAZINE ACETATE SALT | [EINECS(EC#)]
230-845-2 | [Molecular Formula]
C2H8N2O2 | [MDL Number]
MFCD00013141 | [MOL File]
7335-65-1.mol | [Molecular Weight]
92.1 |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow adhering crystals or powder | [Melting point ]
100-102 °C | [Boiling point ]
171.46°C (rough estimate) | [density ]
1.2495 (rough estimate) | [refractive index ]
1.4350 (estimate) | [storage temp. ]
0-6°C | [form ]
Fine Crystalline Powder | [color ]
White | [InChI]
InChI=1S/C2H4O2.H4N2/c1-2(3)4;1-2/h1H3,(H,3,4);1-2H2 | [InChIKey]
YFHNDHXQDJQEEE-UHFFFAOYSA-N | [SMILES]
C(=O)(O)C.NN | [EPA Substance Registry System]
Hydrazine, monoacetate(7335-65-1) |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow adhering crystals or powder | [Uses]
suzuki reaction | [Description]
Hydrazine acetate is an acetate salt of hydrazine. It is used as a reagent to cleavage glycosidic esters and anomeric denitration of carbohydrates. In organic synthesis, it is also used as a building block to prepare various organic derivatives.
| [Definition]
Deformylation with hydrazine acetate was slower than that with hydrazine. Approximately 90% and 5% of the formyl group were removed at 50 and 20 °C, respectively, after 5 h. The rate of deformylation with hydrazine acetate is slower than that with hydrazine alone, but hydrazine acetate would be less harmful to a peptide when the peptide hydrazide is recovered from a formylated peptide hydrazide[1].
| [References]
[1] K. Hojo. “Acylation of hydrazides with acetic acid and formic acid.” Chemical pharmaceutical bulletin 34 1 (2002): 140–2.
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