| Identification | Back Directory | [Name]
N,N'-DI-TERT-BUTYLCARBODIIMIDE | [CAS]
691-24-7 | [Synonyms]
di-tert-butylcarbodiimide
Bis(tert-butyl)carbodiimide
N'-DI-TERT-BUTYLCARBODIIMIDE
1,3-DI-TERT-BUTYLCARBODIIMIDE
N,N'-DI-TERT-BUTYLCARBODIIMIDE
N,N'-Di-tert-butylmethanediimine
N,N'-Di-tert-butylcarbodiimide 99%
ditert-butyl(iminomethylidene)ammonium
N,N'-Bis(1,1-dimethylethyl)carbodiimide
tert-butyl(tert-butyliminomethylene)amine
tert-Butyl[(tert-Butylimino)methylidene]amine
2-Propanamine, N,N'-methanetetraylbis[2-methyl-
N,N'-Methanediylidenebis(2-Methylpropan-2-aMine) | [EINECS(EC#)]
211-719-6 | [Molecular Formula]
C9H18N2 | [MDL Number]
MFCD00010231 | [MOL File]
691-24-7.mol | [Molecular Weight]
154.25 |
| Chemical Properties | Back Directory | [Boiling point ]
48-50 °C12 mm Hg(lit.)
| [density ]
0.800 g/mL at 20 °C(lit.)
| [refractive index ]
n20/D 1.429
| [Fp ]
95 °F
| [form ]
clear liquid | [color ]
Colorless to Almost colorless | [BRN ]
1758049 | [InChI]
InChI=1S/C9H18N2/c1-8(2,3)10-7-11-9(4,5)6/h1-6H3 | [InChIKey]
IDVWLLCLTVBSCS-UHFFFAOYSA-N | [SMILES]
N(=C=NC(C)(C)C)C(C)(C)C |
| Hazard Information | Back Directory | [Uses]
N,N′-Di-tert-butylcarbodiimide can be used:
- As a reagent for the guanylation of aryl amines catalyzed by lanthanum amides.
- To prepare dichloroimidazolidine-4,5-dione by reacting with oxalyl chloride, which is a key intermediate for the synthesis of N,N′-diamidocarbenes.
- To prepare the iridium complex of benzamidine named Ir(FMeppy)2(N,N′-di-tert-butyl-4-methyl-benzamidine).
| [Synthesis Reference(s)]
Tetrahedron Letters, 37, p. 7047, 1996 DOI: 10.1016/0040-4039(96)01593-6 |
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