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ChemicalBook--->CAS DataBase List--->68049-83-2

68049-83-2

68049-83-2 Structure

68049-83-2 Structure
IdentificationBack Directory
[Name]

azafenidin
[CAS]

68049-83-2
[Synonyms]

Evolus
R 6447
C10895
IN-R 6447
Milestone
azafenidin
DPX-R 6447
2-(2,4-dichloro-5-prop-2-ynyloxyphenyl)-5,6,7,8-tetrahydro-1,2,4-triazole(4,3-a)pyridin-3(2H)-one
2-(2,4-dichloro-5-prop-2-ynyloxypnenyl)-5,6,7,8-tetrahy-dro-1,2,4-trizolo [4,3-α] pyridin-3-(2H)-one
1,2,4-Triazolo[4,3-a]pyridin-3(2H)-one, 2-[2,4-dichloro-5-(2-propyn-1-yloxy)phenyl]-5,6,7,8-tetrahydro-
[Molecular Formula]

C15H13Cl2N3O
[MDL Number]

MFCD30720402
[MOL File]

68049-83-2.mol
[Molecular Weight]

322.194
Chemical PropertiesBack Directory
[Melting point ]

168-168.5°
[Boiling point ]

468.9±55.0 °C(Predicted)
[density ]

1.43±0.1 g/cm3(Predicted)
[pka]

2.45±0.20(Predicted)
[EPA Substance Registry System]

Azafeniden (68049-83-2)
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

61-48/22-62-50/53
[Safety Statements ]

53-45-60-61
[Toxicity]

LD50 in rats, mice, bobwhite quail, mallard duck (mg/kg): >5000, >5000, >2500, >2500 orally; in rabbits (mg/kg): >2000 dermally.; LC50 in rats, rainbow trout, blue gill sunfish (mg/l): >5.3, 33, 48 (Amuti)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

2,4-Dichlorophenol-->Erythromycin Estolate-->(-)-MENTHYL CHLOROFORMATE
Hazard InformationBack Directory
[Uses]

Azafenidin is a weed controlling herbicide used in various crops.
[Uses]

Herbicide.
[Definition]

ChEBI: Azafenidin is a triazolopyridine that is 5,6,7,8-tetrahydro[1,2,4]triazolo[4,3-a]pyridin-3(2H)-one which is substituted at position 2 by a 2,4-dichloro-5-(prop-2-yn-1-yloxy)phenyl group. A protoporphyrinogen oxidase inhibitor, it is used as a herbicide to control weeds in fruit crops such as pineapple, citrus, melons, and grapes. Not approved for use within the European Union. It has a role as an EC 1.3.3.4 (protoporphyrinogen oxidase) inhibitor. It is a triazolopyridine, a terminal acetylenic compound and a dichlorobenzene.
[Metabolic pathway]

A common degradation reaction of azafenidin in light, plants and soil is O-dealkylation, and interesting minor reactions in soil are the subsequent methylation of the O-dealkylated degradation product and the reduction of the propynyl group under anaerobic conditions. In soil and light, azafenidin is also readily split to form the triazolinone heterocycle. Azafenidin is readily metabolized in rats and lactating goats through O-dealkylation, hydroxylation of the triazolinone ring in several positions, and glucuronide and sulfate conjugation.
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