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ChemicalBook--->CAS DataBase List--->677736-23-1

677736-23-1

677736-23-1 Structure

677736-23-1 Structure
IdentificationBack Directory
[Name]

CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&
[CAS]

677736-23-1
[Synonyms]

CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC&
CHLORODICARBONYL(1,2,3,4,5-PENTAPHENYLC& ISO 9001：2015 REACH
Chlorodicarbonyl(1,2,3,4,5-pentaphenylcyclopentadienyl)ruthenium(II)
Dicarbonylchloro[(1,2,3,4,5-η)-1,2,3,4,5-pentaphenyl-2,4-cyclopentadien-1-yl]-Ruthenium
Dicarbonylchloro[(1,2,3,4,5,-η:)-1,2,3,4,5-pentaphenylcyclo-2,4-pentadien-1-yl)]ruthenium
[Molecular Formula]

C35H25.2CO.ClRu
[MDL Number]

MFCD09265041
[MOL File]

677736-23-1.mol
[Molecular Weight]

638.125
Chemical PropertiesBack Directory
[Melting point ]

152-167 °C
[storage temp. ]

Inert atmosphere,2-8°C
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
Hazard InformationBack Directory
[Uses]

Reactant for:
  • Synthesis of cyclopentadienyl ruthenium dicarbonyl catalyst
  • Ligand exchange
  • Formation of cyclopentadienyl ruthenium alkoxycarbonylcomplexes with coordinated C:C bonds

Catalyst for:
  • (S)-Selective dynamic kinetic resolution of secondary alcohols
  • Stereoselective synthesis of neonicorinoide pesticide derivatives
  • Divergent asymmetric synthesis of 3,5-disubstituted piperidines
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