| Identification | Back Directory | [Name]
CITRACONIC ACID DIMETHYL ESTER | [CAS]
617-54-9 | [Synonyms]
C05126
DIMETHYL CITRACONATE
dimethylmethylmaleate
Dimethyl methyl maleate
Citraconate de dimethyle
methylmaleicacid,dimethylester
CITRACONIC ACID DIMETHYL ESTER
Methylmaleic acid, dimethyl ester
Maleic acid, methyl-, dimethyl ester
Dimethyl (2Z)-2-methyl-2-butenedioate
Dimethyl cis-1-propene-1,2-dicarboxylate
cis-2-methyl-but-2-enoicaciddimethylester
2-methyl-,dimethylester,(z)-2-butenedioicaci
cis-2-methyl-2-butenedioicacid,dimethylester
2-Methyl-but-2-enedioic acid dimethyl ester, Z
(Z)-2-Methyl-2-butenedioic acid dimethyl ester
2-Butenedioic acid, 2-methyl-, dimethyl ester (Z)-
2-Butenedioic acid, 2-methyl-, dimethyl ester, (2Z)- | [Molecular Formula]
C7H10O4 | [MDL Number]
MFCD00059306 | [MOL File]
617-54-9.mol | [Molecular Weight]
158.15 |
| Safety Data | Back Directory | [Risk Statements ]
36/37/38 | [Safety Statements ]
26-36 | [RTECS ]
GE6700000 | [HS Code ]
2917198090 | [Toxicity]
Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1974). |
| Hazard Information | Back Directory | [Occurrence]
Has apparently not been reported to occur in nature. | [Uses]
Dimethyl Citraconate is a useful synthetic intermediate. It has been used in the synthesis of natural products chaetomellic acid A anhydride and 1,7(Z)- nonadecadiene-2,3-dicarboxylic acid. It is also used to prepare acyclic alkanes by reduction using homogeneous catalysts or biocatalysts. | [Preparation]
By the reaction of methanol with citraconic anhydride in the presence of a catalyst. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 94, p. 9269, 1972 DOI: 10.1021/ja00781a071 |
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